When Mo(CO)6 is heated with triphenylphosphine (PPH3) a number of complexes may form including A and B below. For these complexes; (i) Determine the point groups to which structures A and B belong; (ii) Calculate the number of C-O stretching vibrations expected for each structure. (ii) Calculate the number of Raman active C-O stretching vibrations for each structure. CO PPH3 PPH3 ос—Мо -PPH3 oc-M -Co OC čo OC PPH3 A B

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When Mo(CO)6 is heated with triphenylphosphine (PPH3) a number of
complexes may form including A and B below. For these complexes;
(i)
Determine the point groups to which structures A and B belong;
(ii)
Calculate the number of C-O stretching vibrations expected for
each structure.
(ii)
Calculate the number of Raman active C-O stretching vibrations
for each structure.
CO
PPH3
PPH3
ос—Мо
-PPH3
oc-M
-Co
OC
čo
OC
PPH3
A
B
Transcribed Image Text:When Mo(CO)6 is heated with triphenylphosphine (PPH3) a number of complexes may form including A and B below. For these complexes; (i) Determine the point groups to which structures A and B belong; (ii) Calculate the number of C-O stretching vibrations expected for each structure. (ii) Calculate the number of Raman active C-O stretching vibrations for each structure. CO PPH3 PPH3 ос—Мо -PPH3 oc-M -Co OC čo OC PPH3 A B
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