The carbon-carbon bond length of coordinated ethylene in Ti(15-C5Me5)2(1²-C2H4) is 1.44 A, as determined by X-ray crystal structure analysis. Computational quantum mechanical modelling of the reactive intermediate [Ti(n5-Cp)₂Me(n²-C2H4)]* gives a carbon- carbon bond length of 1.34 Å for the coordinated ethylene ligand. Rationalise this difference in bond length. Sketch relevant molecular orbitals. (CsMes = pentamethylcyclopentadienyl)
The carbon-carbon bond length of coordinated ethylene in Ti(15-C5Me5)2(1²-C2H4) is 1.44 A, as determined by X-ray crystal structure analysis. Computational quantum mechanical modelling of the reactive intermediate [Ti(n5-Cp)₂Me(n²-C2H4)]* gives a carbon- carbon bond length of 1.34 Å for the coordinated ethylene ligand. Rationalise this difference in bond length. Sketch relevant molecular orbitals. (CsMes = pentamethylcyclopentadienyl)
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 116QRT
Related questions
Question
![The carbon-carbon bond length of coordinated ethylene in
Ti(15-C5Me5)2(1²-C2H4) is 1.44 A, as determined by X-ray crystal
structure analysis. Computational quantum mechanical modelling of
the reactive intermediate [Ti(n5-Cp)₂Me(n²-C2H4)]* gives a carbon-
carbon bond length of 1.34 Å for the coordinated ethylene ligand.
Rationalise this difference in bond length. Sketch relevant molecular
orbitals. (CsMes = pentamethylcyclopentadienyl)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fed818df3-a3fa-4105-9924-b593a26e1b48%2F0060fc96-cb23-4a45-8726-da6c9f54d0e6%2Fx4ivrm7_processed.jpeg&w=3840&q=75)
Transcribed Image Text:The carbon-carbon bond length of coordinated ethylene in
Ti(15-C5Me5)2(1²-C2H4) is 1.44 A, as determined by X-ray crystal
structure analysis. Computational quantum mechanical modelling of
the reactive intermediate [Ti(n5-Cp)₂Me(n²-C2H4)]* gives a carbon-
carbon bond length of 1.34 Å for the coordinated ethylene ligand.
Rationalise this difference in bond length. Sketch relevant molecular
orbitals. (CsMes = pentamethylcyclopentadienyl)
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 2 images
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Recommended textbooks for you
![Chemistry: The Molecular Science](https://www.bartleby.com/isbn_cover_images/9781285199047/9781285199047_smallCoverImage.gif)
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
![Principles of Modern Chemistry](https://www.bartleby.com/isbn_cover_images/9781305079113/9781305079113_smallCoverImage.gif)
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
![Chemistry & Chemical Reactivity](https://www.bartleby.com/isbn_cover_images/9781337399074/9781337399074_smallCoverImage.gif)
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
![Chemistry: The Molecular Science](https://www.bartleby.com/isbn_cover_images/9781285199047/9781285199047_smallCoverImage.gif)
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
![Principles of Modern Chemistry](https://www.bartleby.com/isbn_cover_images/9781305079113/9781305079113_smallCoverImage.gif)
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
![Chemistry & Chemical Reactivity](https://www.bartleby.com/isbn_cover_images/9781337399074/9781337399074_smallCoverImage.gif)
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
![Chemistry & Chemical Reactivity](https://www.bartleby.com/isbn_cover_images/9781133949640/9781133949640_smallCoverImage.gif)
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
![Chemistry: An Atoms First Approach](https://www.bartleby.com/isbn_cover_images/9781305079243/9781305079243_smallCoverImage.gif)
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning