When benzophenone is exposed to ultraviolet radiation, it is excited into a singlet state. This singlet changes rapidly into a triplet, which phosphoresces. Triethylamine acts as a quencher for the triplet. In an experiment in the solvent methanol, the phosphorescence intensity varied with amine concentration as shown below. [Q]/(mol·dm−3) 0.0010 0.0050 0.0100 If/(arbitrary units) 0.41 0.25 0.16 A time-resolved laser spectroscopy experiment had also shown that the half-life of the phosphorescence in the absence of a quencher is 38 µs. What is the value of kQ?

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When benzophenone is exposed to ultraviolet radiation, it is excited into a singlet state. This singlet changes rapidly into a triplet, which phosphoresces. Triethylamine acts as a quencher for the triplet. In an experiment in the solvent methanol, the phosphorescence intensity varied with amine concentration as shown below.

[Q]/(mol·dm−3) 0.0010 0.0050 0.0100
If/(arbitrary units) 0.41 0.25 0.16

A time-resolved laser spectroscopy experiment had also shown that the half-life of the phosphorescence in the absence of a quencher is 38 µs. What is the value of kQ?

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