What volume of a 0.217 M hydrobromic acid solution is required to neutralize 29.1 mL of a 0.194 M potassium hydroxide solution? mL hydrobromic acid

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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**Acid-Base Titration Calculation**

To calculate the volume of a 0.217 M hydrobromic acid solution necessary to neutralize 29.1 mL of a 0.194 M potassium hydroxide solution:

1. **Start with the balanced chemical equation:**

   \[
   HBr + KOH \rightarrow KBr + H_2O
   \]
   
   This equation shows that 1 mole of HBr reacts with 1 mole of KOH.

2. **Identify the known values:**

   - Concentration of HBr = 0.217 M
   - Volume of KOH = 29.1 mL
   - Concentration of KOH = 0.194 M

3. **Calculate the moles of KOH:**

   \[
   \text{Moles of KOH} = C_{\text{KOH}} \times V_{\text{KOH}} 
   \]

   Given \( C_{\text{KOH}} = 0.194 \text{ M} \) and \( V_{\text{KOH}} = 29.1 \text{ mL} \) or 0.0291 L:

   \[
   \text{Moles of KOH} = 0.194 \text{ M} \times 0.0291 \text{ L} = 0.0056454 \text{ moles}
   \]

4. **Since the stoichiometric ratio of HBr to KOH is 1:1, moles of HBr required = moles of KOH:**

   \[
   \text{Moles of HBr} = 0.0056454 \text{ moles}
   \]

5. **Calculate the volume of HBr solution needed:**

   \[
   V_{\text{HBr}} = \frac{\text{Moles of HBr}}{C_{\text{HBr}}}
   \]

   Given \( C_{\text{HBr}} = 0.217 \text{ M} \):

   \[
   V_{\text{HBr}} = \frac{0.0056454 \text{ moles}}{0.217 \text{ M}} = 0.02602 \text{ L} \times 1000 = 26.02 \text{ mL}
Transcribed Image Text:**Acid-Base Titration Calculation** To calculate the volume of a 0.217 M hydrobromic acid solution necessary to neutralize 29.1 mL of a 0.194 M potassium hydroxide solution: 1. **Start with the balanced chemical equation:** \[ HBr + KOH \rightarrow KBr + H_2O \] This equation shows that 1 mole of HBr reacts with 1 mole of KOH. 2. **Identify the known values:** - Concentration of HBr = 0.217 M - Volume of KOH = 29.1 mL - Concentration of KOH = 0.194 M 3. **Calculate the moles of KOH:** \[ \text{Moles of KOH} = C_{\text{KOH}} \times V_{\text{KOH}} \] Given \( C_{\text{KOH}} = 0.194 \text{ M} \) and \( V_{\text{KOH}} = 29.1 \text{ mL} \) or 0.0291 L: \[ \text{Moles of KOH} = 0.194 \text{ M} \times 0.0291 \text{ L} = 0.0056454 \text{ moles} \] 4. **Since the stoichiometric ratio of HBr to KOH is 1:1, moles of HBr required = moles of KOH:** \[ \text{Moles of HBr} = 0.0056454 \text{ moles} \] 5. **Calculate the volume of HBr solution needed:** \[ V_{\text{HBr}} = \frac{\text{Moles of HBr}}{C_{\text{HBr}}} \] Given \( C_{\text{HBr}} = 0.217 \text{ M} \): \[ V_{\text{HBr}} = \frac{0.0056454 \text{ moles}}{0.217 \text{ M}} = 0.02602 \text{ L} \times 1000 = 26.02 \text{ mL}
### Neutralization Calculation Example

#### Problem Statement:
What volume of a 0.129 M calcium hydroxide solution is required to neutralize 19.3 mL of a 0.130 M hydrochloric acid solution?

**Answer:** 
\[ \boxed{} \, \text{mL calcium hydroxide} \]

---

**Detailed Explanation:**

This problem involves a neutralization reaction between calcium hydroxide (Ca(OH)₂) and hydrochloric acid (HCl). To solve it, follow these steps:

1. **Write the balanced chemical equation:**

   \[ \text{Ca(OH)}_2 + 2\text{HCl} \rightarrow \text{CaCl}_2 + 2\text{H}_2\text{O} \]

2. **Calculate moles of HCl:**

   \[
   \text{Moles of HCl} = \text{Molarity} \times \text{Volume (L)}
   \]
   \[
   \text{Moles of HCl} = 0.130 \, \text{M} \times 0.0193 \, \text{L} = 0.002509 \, \text{moles}
   \]

3. **Determine moles of Ca(OH)₂ required:**

   From the balanced equation, 1 mole of Ca(OH)₂ reacts with 2 moles of HCl. Therefore, moles of Ca(OH)₂ required:

   \[
   \text{Moles of Ca(OH)}_2 = \frac{0.002509 \, \text{moles}}{2} = 0.001255 \, \text{moles}
   \]

4. **Find the volume of Ca(OH)₂ solution required:**

   \[
   \text{Volume (L)} = \frac{\text{Moles}}{\text{Molarity}}
   \]
   \[
   \text{Volume (L)} = \frac{0.001255 \, \text{moles}}{0.129 \, \text{M}} = 0.009728 \, \text{L}
   \]
   Convert liters to milliliters:

   \[
   \text{Volume (mL)} = 0.009728 \, \text{L}
Transcribed Image Text:### Neutralization Calculation Example #### Problem Statement: What volume of a 0.129 M calcium hydroxide solution is required to neutralize 19.3 mL of a 0.130 M hydrochloric acid solution? **Answer:** \[ \boxed{} \, \text{mL calcium hydroxide} \] --- **Detailed Explanation:** This problem involves a neutralization reaction between calcium hydroxide (Ca(OH)₂) and hydrochloric acid (HCl). To solve it, follow these steps: 1. **Write the balanced chemical equation:** \[ \text{Ca(OH)}_2 + 2\text{HCl} \rightarrow \text{CaCl}_2 + 2\text{H}_2\text{O} \] 2. **Calculate moles of HCl:** \[ \text{Moles of HCl} = \text{Molarity} \times \text{Volume (L)} \] \[ \text{Moles of HCl} = 0.130 \, \text{M} \times 0.0193 \, \text{L} = 0.002509 \, \text{moles} \] 3. **Determine moles of Ca(OH)₂ required:** From the balanced equation, 1 mole of Ca(OH)₂ reacts with 2 moles of HCl. Therefore, moles of Ca(OH)₂ required: \[ \text{Moles of Ca(OH)}_2 = \frac{0.002509 \, \text{moles}}{2} = 0.001255 \, \text{moles} \] 4. **Find the volume of Ca(OH)₂ solution required:** \[ \text{Volume (L)} = \frac{\text{Moles}}{\text{Molarity}} \] \[ \text{Volume (L)} = \frac{0.001255 \, \text{moles}}{0.129 \, \text{M}} = 0.009728 \, \text{L} \] Convert liters to milliliters: \[ \text{Volume (mL)} = 0.009728 \, \text{L}
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