What specific characteristics should a polymeric material attain to be safely implanted? Contrast the benefit/risk of synthetic versus natural polymers.
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- What factors determine whether polymer behavior is predominantly elastic, viscoelastic, or viscoplastic?There are 4 classifications of structural molecular characteristics of polymers - Linear, Network, Crosslinked. What is the final type? Answer:Which statements are correct regarding the mechanical properties of polymers? a. Drawing increases alignment and strength, and decreases ductility (% elongation) b. Annealing increases alignment, strength and elastic modulus c. Increasing temperature results in increased elastic modulus and strength, and decreased elongation d. Decreasing strain rate causes decreased strength and elastic modulus and increased elongation e. A higher degree of crosslinking generally results in decreased percent elongation at break, and increases strength
- In general, polymers have lower strength, hardness, stiffness, density, and temperature resistance compared to ceramics. T or FWhich of the following are incorrect regarding the crystallinity and mechanical behavior of polymers? a. Strain softening happens in elastomers where the deformation gradually leads to a decrease in stiffness under constant strain rate b. As temperature is reduced, necking behavior of plastic tensile bars completely disappears C. The stress-strain curve slope for totally elastic and brittle polymers is always positive d. Heat treatment always results in enhanced polymer strength, modulus, and brittleness e. Semi-crystalline polymers are heat treated to increase crystallinity and improve strength f. Increasing the degree of crystallinity generally increases polymer strength, elastic modulus, and ductility in semi-crystalline polymersWhy are some polymers hygroscopic? How are the mechanical properties affected bymoisture, explain by giving specific examples of polymers and mechanical properties.
- Why do thermoplastic polymers start to turn white as they are plastically deformed?(a) There are three main sub-groups of engineering polymers with distinct differences in their structures. Name these sub- groups; describe their structural differences and bonding mechanisms.An unknown polymer sample was found to have the following molecular weight distribution: Molecular weight range 8,000 - 20,000 20,000 - 32,000 32,000 - 44,000 44,000 - 56,000 56,000 - 68,000 68,000 -80,000 80,000 - 92,000 0.03 Knowing that the monomer is methyl methacrylate, which of the below is the number average degree of polymerization for this polymer sample? Select one: O a. O b. DP 476 O C. DP = 338 DP = 664 O d. DP 544 O e. DP = 801 Xi 0.05 0.15 0.21 0.28 0.18 0.10 Wi 0.02 0.08 0.17 0.29 0.23 0.16 0.05
- Draw stress-strain graphs for two polymers: one is stiffer than the other and exhibits ayield point and the other shows no clear yield point but is much tougher.Given the table below and your judgement for extreme operational conditions, select polymers for the following applications respectively: a dry ice bucket (operating temperature of -78C), a teeth aligner, a hair dryer (operating temperature range of 60-80C) and a phone case. Table 15.2 Melting and Glass Transition Temperatures for Some of the More Common Polymeric Materials Material Polyethylene (low density) Polytetrafluoroethylene Polyethylene (high density) Polypropylene Nylon 6,6 Polyester (PET) Poly(vinyl chloride) Polystyrene Polycarbonate U Glass Transition Temperature [°C (°F)] -110 (-165) -97 (-140) -90 (-130) -18 (0) 57 (135) 69 (155) 87 (190) 100 (212) 150 (300) a. b. c. Nylon, PET, HDPE, PVC Dd. HDP , LDPE, LDPE, PTFE e. LDPE, PTFE, Nylon, polypropylene Melting Temperature [°C (°F)] 115 (240) 327 (620) 137 (279) 175 (347) 265 (510) 265 (510) 212 (415) 240 (465) 265 (510) PTFE, HDPE, HDPE, polypropylene Polypropylene, PET, PTFE, PolypropyleneConnecting rod (as shown below) is a car part that connects engine piston to crankshaft and converts reciprocating motion into rotating motion. It performs under load at high temperature around 150°C. Long carbon fiber thermoplastic composite (LFT) with 30% carbon fiber has been considered to replace metal (steel or aluminum) rod to improve efficiency. Based on the data for different polymers listed in the table above, which polymer(s) would you choose as the polymer matrix for the connecting rod? What is your rationale?