Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Transcribed Image Text:**Question:**
3)
*Insert structure diagram for a theoretical compound here*
4)
*Insert structure diagram for a different theoretical compound here*
**Descriptions:**
- The two images displayed correspond to chemical structures of theoretical organic compounds.
- The third option (labeled as 3) shows a molecule with two benzene rings (hexagonal rings with alternating double bonds) fused to a five-membered ring. Attached to the five-membered ring is a carbonyl group (a carbon double-bonded to an oxygen).
- The fourth option (labeled as 4) depicts another molecule where two benzene rings are fused to a six-membered ring. This central six-membered ring also has a carbonyl group attached.
These structural diagrams illustrate different possible configurations of fused aromatic systems with a carbonyl group, a common feature in organic chemistry. Analyzing and recognizing these differences is essential for understanding molecular behavior and reactivity in various chemical environments.
![**Title: Understanding Organic Reactions: Oxidation Using O₂, NaOH, and Aliquat 336**
**Introduction:**
Welcome to this module on organic reactions! Today, we will explore a specific reaction involving the oxidation of an organic molecule in the presence of O₂, NaOH, and a phase transfer catalyst, Aliquat 336. The goal is to understand the product formed from this reaction and identify it from given options.
**Question:**
What is the product of this reaction?
\[ \text{O}_2, \text{NaOH} \]
\[ \text{Aliquat 336} \]
**Reactant:**
The molecule undergoing the reaction is an organic compound with two fused benzene rings.
**Reaction Conditions:**
1. **O₂ (Oxygen)**: Acts as the oxidizing agent.
2. **NaOH (Sodium Hydroxide)**: Provides the basic environment necessary for the oxidation.
3. **Aliquat 336**: Serves as a phase transfer catalyst to facilitate the reaction.
**Options:**
1. **Option 1:** Depicted as a fused ring structure with no additional functional groups.
2. **Option 2:** Similar to Option 1 but with an additional hydroxyl group (-OH) attached to the central carbon of the molecule.
**Graphical Explanation:**
- **Option 1 Diagram**:
- The structure shows a tricyclic aromatic system combined in a fused manner, without any additional groups.
- **Option 2 Diagram**:
- Similar tricyclic structure as above.
- A hydroxyl group (-OH) attached to the central carbon atom of the molecule.
**Analysis:**
In the given reaction conditions, the presence of O₂ as an oxidizing agent and NaOH indicates the possibility of the addition of an OH group onto the reactant structure. Typically, in such oxidation processes, a hydroxyl group might be introduced to the molecule, altering its structure to form an O-H bond.
**Conclusion:**
Based on the reactants and conditions provided, the reaction results in the introduction of an -OH group to the molecule. Therefore, the correct answer to the question "What is the product of this reaction?" is:
**Option 2,** where the product structure includes an additional hydroxyl group (-OH) on the fused ring structure](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F233396bf-72f6-4e47-8d0d-be3130c6d58a%2F38b11959-92e1-401a-8fe3-c385fb294490%2F0iq06j_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Title: Understanding Organic Reactions: Oxidation Using O₂, NaOH, and Aliquat 336**
**Introduction:**
Welcome to this module on organic reactions! Today, we will explore a specific reaction involving the oxidation of an organic molecule in the presence of O₂, NaOH, and a phase transfer catalyst, Aliquat 336. The goal is to understand the product formed from this reaction and identify it from given options.
**Question:**
What is the product of this reaction?
\[ \text{O}_2, \text{NaOH} \]
\[ \text{Aliquat 336} \]
**Reactant:**
The molecule undergoing the reaction is an organic compound with two fused benzene rings.
**Reaction Conditions:**
1. **O₂ (Oxygen)**: Acts as the oxidizing agent.
2. **NaOH (Sodium Hydroxide)**: Provides the basic environment necessary for the oxidation.
3. **Aliquat 336**: Serves as a phase transfer catalyst to facilitate the reaction.
**Options:**
1. **Option 1:** Depicted as a fused ring structure with no additional functional groups.
2. **Option 2:** Similar to Option 1 but with an additional hydroxyl group (-OH) attached to the central carbon of the molecule.
**Graphical Explanation:**
- **Option 1 Diagram**:
- The structure shows a tricyclic aromatic system combined in a fused manner, without any additional groups.
- **Option 2 Diagram**:
- Similar tricyclic structure as above.
- A hydroxyl group (-OH) attached to the central carbon atom of the molecule.
**Analysis:**
In the given reaction conditions, the presence of O₂ as an oxidizing agent and NaOH indicates the possibility of the addition of an OH group onto the reactant structure. Typically, in such oxidation processes, a hydroxyl group might be introduced to the molecule, altering its structure to form an O-H bond.
**Conclusion:**
Based on the reactants and conditions provided, the reaction results in the introduction of an -OH group to the molecule. Therefore, the correct answer to the question "What is the product of this reaction?" is:
**Option 2,** where the product structure includes an additional hydroxyl group (-OH) on the fused ring structure
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