What is the product of these reactions CTQ#2 (top one first)? о 1, 2 2, 1 1, 1 2,2 CH3 1. OSOA 2. NaHSO3 1. mCPBA 2. Н30 OH 1 OH 111CH 3 OH 2 CH3 ZIOH
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![What is the product of these reactions CTQ#2 (top one first)?
OH
OH
OH
CH3
& &
ICH3
2
0
0 1,2
2,1
1, 1
2,2
-CH3
1. OSO
2. NaHSO3
1. mCPBA
2. H₂O*](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc64aa5c2-ef88-4489-8f6d-441064bfe1a7%2F79991e62-ac54-4f42-8641-d7de6aec506d%2Fheyayx4_processed.jpeg&w=3840&q=75)
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