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- Calculate no of microstate in p³ configurationConsider a molecule having three energy levels as Part A follows: What is the probability that this molecule will be in the lowest-energy state? State Energy (cm-1) Degeneracy Express your answer to three significant figures. 1 1 500. 3 ΑΣφ 3 1500. 5 Imagine a collection of N molecules all at 400. K in which one of these molecules is selected. Pi = Note: k = 0.69503476 cm¬1 . K-1. Submit Previous Answers Request Answer X Incorrect; Try Again; 5 attempts remainingHow many microstates are possible for a d2 configuration, including both weak and strong field limits?
- The number of microstates in the configuration (p1d2) is : 60 675 270 O 3Sometimes it is useful to know the free energy of a photon gas. Calculate the (Helmholtz) free energy directly from the definition F =U - TS. (Express the answer in terms of T and V.)A system consists of three energy levels: a ground level (0 = 0, go = 1); a first excited level (₁ = 2kBT, 91 = 3); and a second excited level (&2 = 8kBT, 92 = 3). Calculate the partition function of the system. .406005 What is the probability for the third energy level? .0024787
- Which of the following statements regarding the Helmholtz function (Helmholtz free energy) are generally true? Select one or more: a. The Helmholtz function is minimized in thermodynamic equilibrium for an isolated system whose energy E, volume V and number of particles N are constant. b. The minimization of the Helmholtz function in thermodynamic equilibrium (under the right conditions) is a consequence of the minimization of the internal energy of the system. c. The minimization of the Helmholtz function in thermodynamic equilibrium is a consequence of the maximization of the total entropy of the system and the environment. d. The Helmholtz function is minimized in thermodynamic equilibrium for a closed system whose temperature T and volume V are constant.What are the salient features of Aufbau principle?P30.12 A set of 13 particles occupies states with energies of 0, 100., and 200. cm ¹. Calculate the total energy and number of microstates for the following energy configurations: 5, and a2 0 3, and a2 1 a. do b. do = 8, a₁ = c. ao = = = 9, a1 10, a₁ = 1, and a2 = = 2 Do any of these configurations correspond to the Boltzmann distribution?
- 4. What is the form of the total vibrational partition function for a polyatomic molecule?Transitions states occur at a saddle point. True or False. Why?Transitions in the rotational spectrum of the sodium chloride molecule, 23NA3ºCI, which is present in the interstellar medium, are observed at frequencies of 247.2, 260.2, 273.2, 286.2 and 299.2 GHz. Determine the bond length of a sodium chloride molecule. A. 1.09 Å В. 2.37 Å С. 5.62 Å D. 2.01 Å
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