We know that for an ideal gas Cp,m = Cv,m + R. %3D The general relationship for any gas can be written, for 1 mole, as Cp,m = Cy,m + (Yn") a²VmT` k (equation-1) Where Vm is the molar volume (the volume of 1 mole of the gas, V/n). a is the coefficient of volume expansion and is given by: a = where the partial derivative of V with respect to T is calculated ƏT assuming P is constant And K is the coefficient of volume expansion and is given by: k = GO where the partial derivative of V with respect to P is calculated assuming T is constant. Note the minus in the definition. Prove that equation-1 reduces to the result derived in class for an ideal gas by calculating (A²V¼T\ k
We know that for an ideal gas Cp,m = Cv,m + R. %3D The general relationship for any gas can be written, for 1 mole, as Cp,m = Cy,m + (Yn") a²VmT` k (equation-1) Where Vm is the molar volume (the volume of 1 mole of the gas, V/n). a is the coefficient of volume expansion and is given by: a = where the partial derivative of V with respect to T is calculated ƏT assuming P is constant And K is the coefficient of volume expansion and is given by: k = GO where the partial derivative of V with respect to P is calculated assuming T is constant. Note the minus in the definition. Prove that equation-1 reduces to the result derived in class for an ideal gas by calculating (A²V¼T\ k
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![We know that for an ideal gas Cp,m = Cv,m + R.
%3D
The general relationship for any gas can be written, for 1 mole, as
Cp,m = Cy,m +
(Yn")
a²VmT`
k
(equation-1)
Where Vm is the molar volume (the volume of 1 mole of the gas, V/n).
a is the coefficient of volume expansion and is given by:
a =
where the partial derivative of V with respect to T is calculated
ƏT
assuming P is constant
And K is the coefficient of volume expansion and is given by:
k =
GO where the partial derivative of V with respect to P is calculated
assuming T is constant. Note the minus in the definition.
Prove that equation-1 reduces to the result derived in class for an ideal gas by calculating
(A²V¼T\
k](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F12958458-96f4-4f8c-8330-c5f03483b490%2Fbb07e6d7-5e90-4610-ae10-e05a5a5184de%2F9k6xzjb_processed.png&w=3840&q=75)
Transcribed Image Text:We know that for an ideal gas Cp,m = Cv,m + R.
%3D
The general relationship for any gas can be written, for 1 mole, as
Cp,m = Cy,m +
(Yn")
a²VmT`
k
(equation-1)
Where Vm is the molar volume (the volume of 1 mole of the gas, V/n).
a is the coefficient of volume expansion and is given by:
a =
where the partial derivative of V with respect to T is calculated
ƏT
assuming P is constant
And K is the coefficient of volume expansion and is given by:
k =
GO where the partial derivative of V with respect to P is calculated
assuming T is constant. Note the minus in the definition.
Prove that equation-1 reduces to the result derived in class for an ideal gas by calculating
(A²V¼T\
k
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