Wavenumber em A 18,000 cm B = 27,000 cm e the appropriate Tanabe-Sugano diagram to assign the absorbance band ectrum above. hich transition is not observed in the spectrum? Suggest a reason why only sorption bands are observed. termine the B Racah parameter. Show all calculations.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Consider the spectrum of (Co(H20)6]** in aqueous solution below and answer the questions that
follow:
0.14
0.12
0.1
0.08
0.06
0.04
0.02
Wavenumber em
A = 18,000 cm
B = 27,000 cm
(a) Use the appropriate Tanabe-Sugano diagram to assign the absorbance bands in the
spectrum above.
(b) Which transition is not observed in the spectrum? Suggest a reason why only two
absorption bands are observed.
(c)
Determine the B Racah parameter. Show all calculations.
(d)
Determine the Ao parameter. Show all calculations.
Absorbance
Transcribed Image Text:Consider the spectrum of (Co(H20)6]** in aqueous solution below and answer the questions that follow: 0.14 0.12 0.1 0.08 0.06 0.04 0.02 Wavenumber em A = 18,000 cm B = 27,000 cm (a) Use the appropriate Tanabe-Sugano diagram to assign the absorbance bands in the spectrum above. (b) Which transition is not observed in the spectrum? Suggest a reason why only two absorption bands are observed. (c) Determine the B Racah parameter. Show all calculations. (d) Determine the Ao parameter. Show all calculations. Absorbance
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