Vei to ーエ Eדיייי 2.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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 The green pathway: the electrons flow from the negatively charged oxygen atom to the C-O bond, the C=c bond to the C-C bond, the C=C bond to the carbon atom, and the carbon atom to the hydrogen atom than the oxygen atom 

(A) I dont understand why is the proton transfer from the hydrogen atom to the oxygen atom needed 

(B) I do not understand why cant the electron flow directly from the O - to the oxygen atom in H2O? 

Vei to
ーエ
Eדיייי
2.
Transcribed Image Text:Vei to ーエ Eדיייי 2.
Expert Solution
Step 1

Negative charge on electronegative atom is more reasonable (stable) than electropositive atom.

The less stable ion is faster in reaction so the formation of O-H is slower and C-H is faster.

Lowest energy product is more stable than highest energy product.

In organic reactions, the mechanism leads to the formation of lowest energy products.

Therefore, the direction of electron flow to H2O is results the formation of O-H bond and electron flow to C-O, C=C is leads to the formation of C-H bond.

C-H bond has lowest energy and lowest electronegativity difference than O-H bond therefor,  the direction of electron flow through C-O, C=C and C-C in the reaction.

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