van der Waals' equation

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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According to the ideal gas law, a 10.27 mol sample of nitrogen gas in a 0.8385 L container at
499.5 K should exert a pressure of 502.0 atm. What is the percent difference between the
pressure calculated using the van der Waals' equation and the ideal pressure? For N₂ gas, a =
1.390 L²atm/mol² and b = 3.910×10-² L/mol.
Percent difference
%
=
Pideal P
van der Waals
Pideal+Pvan der Waals
2
x 100
Transcribed Image Text:According to the ideal gas law, a 10.27 mol sample of nitrogen gas in a 0.8385 L container at 499.5 K should exert a pressure of 502.0 atm. What is the percent difference between the pressure calculated using the van der Waals' equation and the ideal pressure? For N₂ gas, a = 1.390 L²atm/mol² and b = 3.910×10-² L/mol. Percent difference % = Pideal P van der Waals Pideal+Pvan der Waals 2 x 100
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