Using Le Chatelier's principle, at equilibrium, how would ion concentrations change for the following balanced reactions after adding more of something (given below)? Fe+3   +   SCN-1     ↔      Fe(SCN)+2 a. add Fe(NO3)3 b. add KSCN c. add NaOH Ni+2   +   6NH3  ↔      Ni(NH3)6+2 d. add HCl e. add NH4OH HInaq  +  H2O   ↔  H3O+  +  Inaq-1 f. add HCl g. add NaOH

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Using Le Chatelier's principle, at equilibrium, how would ion concentrations change for the following balanced reactions after adding more of something (given below)?

Fe+3   +   SCN-1     ↔      Fe(SCN)+2

a. add Fe(NO3)3

b. add KSCN

c. add NaOH

Ni+2   +   6NH3  ↔      Ni(NH3)6+2

d. add HCl

e. add NH4OH

HInaq  +  H2O   ↔  H3O+  +  Inaq-1

f. add HCl

g. add NaOH

Expert Solution
Step 1

We konw that as per  Le Chatelier's Principle, the system will react to minimize the stress , and attend equillibrium state.

As per given reaction

                                  Fe+3   +   SCN-1     ↔      Fe(SCN)+2

A) Add Fe(NO3)3      

    • Fe(NO3)  Fe  +3    + 3(NO3)-1

Here in above reaction  concentration of Fe  +3  increases when we add Fe(NO3)3 in main reaction. 

Acoording to Le Chatelier's Principle equilibrium shifts right hand side. So in reaction  product will be formed more that is Fe(SCN)+2  

B. Add KSCN 

  •   KSCN K+ + SCN -1 Here in above reaction concentration of SCN -1 also increases when we add kscn in mailn reaction As  SCN -1  increases reactant will be increases equilibrium shift towards right hand side and product will be more formed. 

C. Add NaOH 

Adittion of NaOH it will form Fe(OH)3 as precipitates and intesity  of that  Fe(SCN)+2  complex will decreased so and equilibrium of the reaction will shif left hand side means towords reactant. 

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