Using Equation 8-7 and Table 8-1 in your text, calculate the activity coefficient for Ca in a 0.01 M solution of Ca(ClO4)2?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Using Equation 8-7 and Table 8-1 in your text, calculate the activity coefficient for Ca in a 0.01 M solution of Ca(ClO4)2?

 
**Table 8-1: Activity Coefficients for Aqueous Solutions at 25°C**

This table provides activity coefficients for various ions in aqueous solutions at a temperature of 25°C, organized by ionic strength and charge.

**Headers:**
- **Ion Size (α, pm):** The effective diameter of the ion.
- **Ionic Strength (μ, M):** The concentration of ions in a solution, measured in molarity (0.001, 0.005, 0.01, 0.05, 0.1 M).

**Ion Charges and Values:**

1. **Charge = ±1:**
   - **Ion:** H⁺
     - **Ion Size:** 900 pm
     - **Activity Coefficients:** 0.900, 0.967, 0.933, 0.914, 0.860, 0.830
   - Other monovalent ions include (CH₃)₄N⁺, (C₂H₅)₄N⁺, Na⁺, OH⁻, Cl⁻, etc., with ion sizes ranging from 300 to 800 pm and varying activity coefficients based on ionic strength.

2. **Charge = ±2:**
   - **Ions:** Mg²⁺, Be²⁺
     - **Ion Size:** 800 pm
     - **Activity Coefficients:** 0.800, 0.872, 0.755, 0.690, 0.520, 0.455
   - Other divalent ions include Co²⁺, Zn²⁺, Cu²⁺, etc., with sizes from 400 to 800 pm.

3. **Charge = ±3:**
   - **Ions:** Al³⁺, Fe³⁺, Sc³⁺, etc.
     - **Ion Size:** 900 pm
     - **Activity Coefficients:** 0.900, 0.738, 0.514, 0.445, 0.245, 0.158

4. **Charge = ±4:**
   - **Ions:** Th⁴⁺, Zr⁴⁺, Ce⁴⁺, etc.
     - **Ion Size:** 1100 pm
     - **Activity Coefficients:** 1
Transcribed Image Text:**Table 8-1: Activity Coefficients for Aqueous Solutions at 25°C** This table provides activity coefficients for various ions in aqueous solutions at a temperature of 25°C, organized by ionic strength and charge. **Headers:** - **Ion Size (α, pm):** The effective diameter of the ion. - **Ionic Strength (μ, M):** The concentration of ions in a solution, measured in molarity (0.001, 0.005, 0.01, 0.05, 0.1 M). **Ion Charges and Values:** 1. **Charge = ±1:** - **Ion:** H⁺ - **Ion Size:** 900 pm - **Activity Coefficients:** 0.900, 0.967, 0.933, 0.914, 0.860, 0.830 - Other monovalent ions include (CH₃)₄N⁺, (C₂H₅)₄N⁺, Na⁺, OH⁻, Cl⁻, etc., with ion sizes ranging from 300 to 800 pm and varying activity coefficients based on ionic strength. 2. **Charge = ±2:** - **Ions:** Mg²⁺, Be²⁺ - **Ion Size:** 800 pm - **Activity Coefficients:** 0.800, 0.872, 0.755, 0.690, 0.520, 0.455 - Other divalent ions include Co²⁺, Zn²⁺, Cu²⁺, etc., with sizes from 400 to 800 pm. 3. **Charge = ±3:** - **Ions:** Al³⁺, Fe³⁺, Sc³⁺, etc. - **Ion Size:** 900 pm - **Activity Coefficients:** 0.900, 0.738, 0.514, 0.445, 0.245, 0.158 4. **Charge = ±4:** - **Ions:** Th⁴⁺, Zr⁴⁺, Ce⁴⁺, etc. - **Ion Size:** 1100 pm - **Activity Coefficients:** 1
To interpolate a value of \( y \), we can set up a proportion:

\[
\frac{\text{Unknown } y \text{ interval}}{\Delta y} = \frac{\text{known } x \text{ interval}}{\Delta x}
\]

Interpolation:

\[
\frac{0.83 - y}{0.83 - 0.67} = \frac{20 - 16}{20 - 10} \implies y = 0.766
\]

For \( x = 16 \), our estimate of \( y \) is 0.766.
Transcribed Image Text:To interpolate a value of \( y \), we can set up a proportion: \[ \frac{\text{Unknown } y \text{ interval}}{\Delta y} = \frac{\text{known } x \text{ interval}}{\Delta x} \] Interpolation: \[ \frac{0.83 - y}{0.83 - 0.67} = \frac{20 - 16}{20 - 10} \implies y = 0.766 \] For \( x = 16 \), our estimate of \( y \) is 0.766.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps

Blurred answer
Knowledge Booster
Equilibrium Concepts in Analytical Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY