Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Using Equation 8-7 and Table 8-1 in your text, calculate the activity coefficient for Ca in a 0.01 M solution of Ca(ClO4)2?
![**Table 8-1: Activity Coefficients for Aqueous Solutions at 25°C**
This table provides activity coefficients for various ions in aqueous solutions at a temperature of 25°C, organized by ionic strength and charge.
**Headers:**
- **Ion Size (α, pm):** The effective diameter of the ion.
- **Ionic Strength (μ, M):** The concentration of ions in a solution, measured in molarity (0.001, 0.005, 0.01, 0.05, 0.1 M).
**Ion Charges and Values:**
1. **Charge = ±1:**
- **Ion:** H⁺
- **Ion Size:** 900 pm
- **Activity Coefficients:** 0.900, 0.967, 0.933, 0.914, 0.860, 0.830
- Other monovalent ions include (CH₃)₄N⁺, (C₂H₅)₄N⁺, Na⁺, OH⁻, Cl⁻, etc., with ion sizes ranging from 300 to 800 pm and varying activity coefficients based on ionic strength.
2. **Charge = ±2:**
- **Ions:** Mg²⁺, Be²⁺
- **Ion Size:** 800 pm
- **Activity Coefficients:** 0.800, 0.872, 0.755, 0.690, 0.520, 0.455
- Other divalent ions include Co²⁺, Zn²⁺, Cu²⁺, etc., with sizes from 400 to 800 pm.
3. **Charge = ±3:**
- **Ions:** Al³⁺, Fe³⁺, Sc³⁺, etc.
- **Ion Size:** 900 pm
- **Activity Coefficients:** 0.900, 0.738, 0.514, 0.445, 0.245, 0.158
4. **Charge = ±4:**
- **Ions:** Th⁴⁺, Zr⁴⁺, Ce⁴⁺, etc.
- **Ion Size:** 1100 pm
- **Activity Coefficients:** 1](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F01f94f9d-801f-4be9-a5b8-e1805f66d76a%2Ffd480ebc-a5a4-4a2e-856f-ad141ed676f6%2Fyd1by2.jpeg&w=3840&q=75)
Transcribed Image Text:**Table 8-1: Activity Coefficients for Aqueous Solutions at 25°C**
This table provides activity coefficients for various ions in aqueous solutions at a temperature of 25°C, organized by ionic strength and charge.
**Headers:**
- **Ion Size (α, pm):** The effective diameter of the ion.
- **Ionic Strength (μ, M):** The concentration of ions in a solution, measured in molarity (0.001, 0.005, 0.01, 0.05, 0.1 M).
**Ion Charges and Values:**
1. **Charge = ±1:**
- **Ion:** H⁺
- **Ion Size:** 900 pm
- **Activity Coefficients:** 0.900, 0.967, 0.933, 0.914, 0.860, 0.830
- Other monovalent ions include (CH₃)₄N⁺, (C₂H₅)₄N⁺, Na⁺, OH⁻, Cl⁻, etc., with ion sizes ranging from 300 to 800 pm and varying activity coefficients based on ionic strength.
2. **Charge = ±2:**
- **Ions:** Mg²⁺, Be²⁺
- **Ion Size:** 800 pm
- **Activity Coefficients:** 0.800, 0.872, 0.755, 0.690, 0.520, 0.455
- Other divalent ions include Co²⁺, Zn²⁺, Cu²⁺, etc., with sizes from 400 to 800 pm.
3. **Charge = ±3:**
- **Ions:** Al³⁺, Fe³⁺, Sc³⁺, etc.
- **Ion Size:** 900 pm
- **Activity Coefficients:** 0.900, 0.738, 0.514, 0.445, 0.245, 0.158
4. **Charge = ±4:**
- **Ions:** Th⁴⁺, Zr⁴⁺, Ce⁴⁺, etc.
- **Ion Size:** 1100 pm
- **Activity Coefficients:** 1
![To interpolate a value of \( y \), we can set up a proportion:
\[
\frac{\text{Unknown } y \text{ interval}}{\Delta y} = \frac{\text{known } x \text{ interval}}{\Delta x}
\]
Interpolation:
\[
\frac{0.83 - y}{0.83 - 0.67} = \frac{20 - 16}{20 - 10} \implies y = 0.766
\]
For \( x = 16 \), our estimate of \( y \) is 0.766.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F01f94f9d-801f-4be9-a5b8-e1805f66d76a%2Ffd480ebc-a5a4-4a2e-856f-ad141ed676f6%2F0v77hu_processed.jpeg&w=3840&q=75)
Transcribed Image Text:To interpolate a value of \( y \), we can set up a proportion:
\[
\frac{\text{Unknown } y \text{ interval}}{\Delta y} = \frac{\text{known } x \text{ interval}}{\Delta x}
\]
Interpolation:
\[
\frac{0.83 - y}{0.83 - 0.67} = \frac{20 - 16}{20 - 10} \implies y = 0.766
\]
For \( x = 16 \), our estimate of \( y \) is 0.766.
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