Typical "hard" water contains about 80.2 mg of Ca2* per liter. Calculate the maximum concentration of fluoride ion which could be present in hard water. Ksp of CaF2 = 4.00 x 10-11 4.53 x 10-5 M fluoride ions 1.41 x 10-4 M fluoride ions None of these 4.96 x 10-3 M fluoride ions 2.00 x 10-8 M fluoride ions 0.0291 M fluoride ions

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Chapter1: Chemical Foundations
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**Problem Statement:**

Typical "hard" water contains about 80.2 mg of Ca²⁺ per liter. Calculate the maximum concentration of fluoride ion which could be present in hard water. The solubility product constant (Kₛₚ) of CaF₂ is 4.00 x 10⁻¹¹.

**Multiple Choice Answers:**

1. ○ 4.53 x 10⁻⁵ M fluoride ions
2. ○ 1.41 x 10⁻⁴ M fluoride ions
3. ○ None of these
4. ○ 4.96 x 10⁻³ M fluoride ions
5. ○ 2.00 x 10⁻⁸ M fluoride ions
6. ○ 0.0291 M fluoride ions

**Explanation:**

To solve this problem, we need to assess the conditions where calcium fluoride (CaF₂) might precipitate or dissolve in the presence of calcium ions (Ca²⁺) and fluoride ions (F⁻) in the given water sample. This involves calculating the fluoride ion concentration that results in equilibrium based on the provided Kₛₚ value.
Transcribed Image Text:**Problem Statement:** Typical "hard" water contains about 80.2 mg of Ca²⁺ per liter. Calculate the maximum concentration of fluoride ion which could be present in hard water. The solubility product constant (Kₛₚ) of CaF₂ is 4.00 x 10⁻¹¹. **Multiple Choice Answers:** 1. ○ 4.53 x 10⁻⁵ M fluoride ions 2. ○ 1.41 x 10⁻⁴ M fluoride ions 3. ○ None of these 4. ○ 4.96 x 10⁻³ M fluoride ions 5. ○ 2.00 x 10⁻⁸ M fluoride ions 6. ○ 0.0291 M fluoride ions **Explanation:** To solve this problem, we need to assess the conditions where calcium fluoride (CaF₂) might precipitate or dissolve in the presence of calcium ions (Ca²⁺) and fluoride ions (F⁻) in the given water sample. This involves calculating the fluoride ion concentration that results in equilibrium based on the provided Kₛₚ value.
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