Use the systematic treatment of equilibrium to calculate the concentration of Ba2+ in acidic solution, if its concentration is governed by the following equilibria – BaSO4(s) → Ba2+ + SO2-4 Ksp = 1.1 x 10-10 SO2-4 +H2O → HSO-4 +OH- Kb = 9.8 x 10–13

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Use the systematic treatment of equilibrium to
calculate the concentration of Ba2+ in acidic
solution, if its concentration is governed by
the following equilibria -
BaSO4(s) → Ba2+ + SO2-4
Ksp = 1.1 x 10-10
SO2-4 +H2O → HSO-4 +OH-
Kb = 9.8 x 10-13
Ba2+ + SO2-4 → BaSO4(aq)
Kf = 1.9 x 101
Hint: Since the pH is fixed at 1.89, the charge
balance is invalidated. Use the mass balance
for your calculation.
Transcribed Image Text:Use the systematic treatment of equilibrium to calculate the concentration of Ba2+ in acidic solution, if its concentration is governed by the following equilibria - BaSO4(s) → Ba2+ + SO2-4 Ksp = 1.1 x 10-10 SO2-4 +H2O → HSO-4 +OH- Kb = 9.8 x 10-13 Ba2+ + SO2-4 → BaSO4(aq) Kf = 1.9 x 101 Hint: Since the pH is fixed at 1.89, the charge balance is invalidated. Use the mass balance for your calculation.
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