Use the References to access important values if needed for this question. Enter electrons as e. Use smallest possible integer coefficients. States are not required. If a box is not needed, leave it blank. Standard Reduction Potentials (Volts) at 25 °C Br₂ (1) + 2e →→→ 2 Br* (aq) 1.080 O₂(g) + 4 H3O+(aq) + 4 e¯ →→→ 6 H₂O(1) 2 H₂O(l) +2 e* → H₂(g) + 2 OH-(aq) La³+ (aq) + 3 e→→→→La (s) 1.229 -0.828 -2.370 A 0.117 M neutral aqueous LaBr3 solution is electrolyzed under 1 atm pressure using platinum electrodes. (a) Write the half-reactions expected to occur, taking into account the effect of the non-standard conditions on the electrode potentia Half-reaction at anode:

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Chapter1: Chemical Foundations
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Half-reaction at anode:
Half-reaction at cathode:
+
Use the References to access important values if needed for this question.
+
Enter electrons as e.
Use smallest possible integer coefficients.
States are not required. If a box is not needed, leave it blank.
Standard Reduction Potentials (Volts) at 25 °C
1.080
Br₂ (1) + 2 e¯ →→→ 2 Br¨ (aq)
O₂(g) + 4 H3O+(aq) + 4 e¯
A 0.117 M neutral aqueous LaBr3 solution is electrolyzed under 1 atm pressure using platinum electrodes.
(a) Write the half-reactions expected to occur, taking into account the effect of the non-standard conditions on the electrode potentials.
2 H₂O(1) + 2 e¨ ·
H₂(g) + 2 OH-(aq) -0.828
La³+ (aq) + 3 e¯ →→→→La (s)
-2.370
+
6 H₂O(1)
+
(b) What is the expected decomposition potential?
1.229
+
+
+
+
Transcribed Image Text:Half-reaction at anode: Half-reaction at cathode: + Use the References to access important values if needed for this question. + Enter electrons as e. Use smallest possible integer coefficients. States are not required. If a box is not needed, leave it blank. Standard Reduction Potentials (Volts) at 25 °C 1.080 Br₂ (1) + 2 e¯ →→→ 2 Br¨ (aq) O₂(g) + 4 H3O+(aq) + 4 e¯ A 0.117 M neutral aqueous LaBr3 solution is electrolyzed under 1 atm pressure using platinum electrodes. (a) Write the half-reactions expected to occur, taking into account the effect of the non-standard conditions on the electrode potentials. 2 H₂O(1) + 2 e¨ · H₂(g) + 2 OH-(aq) -0.828 La³+ (aq) + 3 e¯ →→→→La (s) -2.370 + 6 H₂O(1) + (b) What is the expected decomposition potential? 1.229 + + + +
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