If the voltmeter was replaced with a resistor (that allows current to flow) and the current is measured to be a constant 1.250 A, it would take [Select] If the concentrations were changed to [Mg] -5.00 M and [Ag] -0.0100 M, the cell potential would then be [Select] to deposit 0.500 g of metal on the cathode.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Just the last 2 blocks. Use table if needed in first pic.
### Question 1

**Diagram Explanation:**

The diagram shows an electrochemical cell with the following components:
- **Voltmeter:** Measures the potential difference across the cell.
- **Salt bridge:** Maintains electrical neutrality by allowing ions to flow between the solutions.
- **Electrodes:** 
  - **Left:** Magnesium electrode in a solution of \( \text{Mg(NO}_3\text{)}_2 \).
  - **Right:** Silver electrode in a solution of \( \text{AgNO}_3 \).

**Questions and Answers:**

1. **In the balanced cell reaction, the number of electrons transferred is:**  
   \( 2 \)

2. **The electrons would flow:**  
   From the Mg electrode to the Ag electrode.

3. **The standard (assuming 1 M concentrations) cell potential is:**  
   \( 1.76 \, \text{V} \)

4. **The change in standard Gibbs' Energy, \( \Delta G \), for the overall reaction would be:**  
   \( 609 \, \text{kJ/mol} \)

5. **The silver electrode gains mass by:**  
   \[ \text{Select appropriate amount (not provided)} \]

6. **If the voltmeter was replaced with a resistor (that allows current to flow) and the current is measured to be a constant 1.250 A, it would take:**  
   \[ \text{Select appropriate time (not provided)} \]  
   To deposit 0.500 g of metal on the cathode.

7. **If the concentrations were changed to \([ \text{Mg}^{2+} ] = 5.00 \, \text{M}\) and \([ \text{Ag}^+ ] = 0.0100 \, \text{M}\), the cell potential would then be:**  
   \[ \text{Select new cell potential (not provided)} \]

**Question 2**

\[ \text{Please refer to the next section for detailed content (not visible in the image).} \]
Transcribed Image Text:### Question 1 **Diagram Explanation:** The diagram shows an electrochemical cell with the following components: - **Voltmeter:** Measures the potential difference across the cell. - **Salt bridge:** Maintains electrical neutrality by allowing ions to flow between the solutions. - **Electrodes:** - **Left:** Magnesium electrode in a solution of \( \text{Mg(NO}_3\text{)}_2 \). - **Right:** Silver electrode in a solution of \( \text{AgNO}_3 \). **Questions and Answers:** 1. **In the balanced cell reaction, the number of electrons transferred is:** \( 2 \) 2. **The electrons would flow:** From the Mg electrode to the Ag electrode. 3. **The standard (assuming 1 M concentrations) cell potential is:** \( 1.76 \, \text{V} \) 4. **The change in standard Gibbs' Energy, \( \Delta G \), for the overall reaction would be:** \( 609 \, \text{kJ/mol} \) 5. **The silver electrode gains mass by:** \[ \text{Select appropriate amount (not provided)} \] 6. **If the voltmeter was replaced with a resistor (that allows current to flow) and the current is measured to be a constant 1.250 A, it would take:** \[ \text{Select appropriate time (not provided)} \] To deposit 0.500 g of metal on the cathode. 7. **If the concentrations were changed to \([ \text{Mg}^{2+} ] = 5.00 \, \text{M}\) and \([ \text{Ag}^+ ] = 0.0100 \, \text{M}\), the cell potential would then be:** \[ \text{Select new cell potential (not provided)} \] **Question 2** \[ \text{Please refer to the next section for detailed content (not visible in the image).} \]
# Standard Reduction Potentials (25 °C)

This table lists the standard reduction potentials for various half-reactions at 25 °C. The reduction potentials are given in volts (V).

| Half-Reaction                        | E° (V)  |
|--------------------------------------|---------|
| Co³⁺(aq) + e⁻ → Co²⁺(aq)             | +1.92   |
| Au³⁺(aq) + 3e⁻ → Au(s)               | +1.498  |
| Cl₂(g) + 2e⁻ → 2Cl⁻(aq)              | +1.36   |
| Pd²⁺(aq) + 2e⁻ → Pd(s)               | +0.915  |
| Ag⁺(aq) + e⁻ → Ag(s)                 | +0.80   |
| I₂(s) + 2e⁻ → 2I⁻(aq)                | +0.54   |
| Cu²⁺(aq) + 2e⁻ → Cu(s)               | +0.34   |
| Cu⁺(aq) + e⁻ → Cu(s)                 | +0.153  |
| 2H⁺(aq) + 2e⁻ → H₂(g)                |  0.00   |
| Pb²⁺(aq) + 2e⁻ → Pb(s)               | -0.13   |
| Ni²⁺(aq) + 2e⁻ → Ni(s)               | -0.232  |
| Cd²⁺(aq) + 2e⁻ → Cd(s)               | -0.40   |
| Fe²⁺(aq) + 2e⁻ → Fe(s)               | -0.44   |
| Cr³⁺(aq) + 3e⁻ → Cr(s)               | -0.740  |
| Zn²⁺(aq) + 2e⁻ → Zn(s)               | -0.76   |
| Mn²⁺(aq) + 2e⁻ → Mn(s)               | -1.185  |
| Ti²⁺(aq) + 2e⁻ → Ti(s)               | -1.630
Transcribed Image Text:# Standard Reduction Potentials (25 °C) This table lists the standard reduction potentials for various half-reactions at 25 °C. The reduction potentials are given in volts (V). | Half-Reaction | E° (V) | |--------------------------------------|---------| | Co³⁺(aq) + e⁻ → Co²⁺(aq) | +1.92 | | Au³⁺(aq) + 3e⁻ → Au(s) | +1.498 | | Cl₂(g) + 2e⁻ → 2Cl⁻(aq) | +1.36 | | Pd²⁺(aq) + 2e⁻ → Pd(s) | +0.915 | | Ag⁺(aq) + e⁻ → Ag(s) | +0.80 | | I₂(s) + 2e⁻ → 2I⁻(aq) | +0.54 | | Cu²⁺(aq) + 2e⁻ → Cu(s) | +0.34 | | Cu⁺(aq) + e⁻ → Cu(s) | +0.153 | | 2H⁺(aq) + 2e⁻ → H₂(g) | 0.00 | | Pb²⁺(aq) + 2e⁻ → Pb(s) | -0.13 | | Ni²⁺(aq) + 2e⁻ → Ni(s) | -0.232 | | Cd²⁺(aq) + 2e⁻ → Cd(s) | -0.40 | | Fe²⁺(aq) + 2e⁻ → Fe(s) | -0.44 | | Cr³⁺(aq) + 3e⁻ → Cr(s) | -0.740 | | Zn²⁺(aq) + 2e⁻ → Zn(s) | -0.76 | | Mn²⁺(aq) + 2e⁻ → Mn(s) | -1.185 | | Ti²⁺(aq) + 2e⁻ → Ti(s) | -1.630
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