Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy A.S. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A B C observations Crystallization of a pure compound is spontaneous only below -25. °C. The reverse of this reaction is always spontaneous. This reaction is always spontaneous, but proceeds slower at temperatures above 32. °C. AH is conclusions AS is ΔΗ is AS is ΔΗ is AS is X (pick one) (pick one) (pick one) (pick one) (pick one) (pick one) Ⓒ

Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy A.S. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A B C observations Crystallization of a pure compound is spontaneous only below -25. °C. The reverse of this reaction is always spontaneous. This reaction is always spontaneous, but proceeds slower at temperatures above 32. °C. AH is conclusions AS is ΔΗ is AS is ΔΗ is AS is X (pick one) (pick one) (pick one) (pick one) (pick one) (pick one) Ⓒ

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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1. A potential chemical reaction at 25.0 °C has a ΔHrxn of 147.5 kJ and a ΔSrxn of -386.9 J/K. What is the ΔGrxn in kJ. (Enter answer to 3 significant figures and include no units in your answer) Also, what is true about the potential reaction in the previous problem? a. spontaneous b. illegal c. combustive d. nonspontaneous
Read the descriptions of physical or chemical changes in the table below. Then decide whether the change will be spontaneous, if you can. Change An exothermic chemical reaction between a solid and a liquid results in gaseous products. A solid precipitates from a solution, absorbing heat as it does so. A gas expands, absorbing heat from its surroundings. Is this change spontaneous? Yes. No. Can't decide with information given. Yes. No. O Can't decide with information given. Yes. No. Can't decide with information given. X
Sublimation is an example of a process for which a. ΔH is negative and ΔS is positive at all temperatures. b. ΔH, ΔS, and ΔG are positive at all temperatures. c. ΔH and ΔS are positive at all temperatures. d. ΔH is positive and ΔS is negative at all temperatures. e. ΔH, ΔS, and ΔG are negative at all temperatures.
Chemistry Above what temperature does the following reaction become non-spontaneous? 2 H₂S(g) + 3 O₂(g) → 2 SO₂(g) + 2 H₂O(g) AH = -1036 kJ; AS = -153.2 J/K O 158.7 K This reaction is nonspontaneous at all temperatures. O 298 K This reaction is spontaneous at all temperatures O 6.762 × 103 K
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy A.S. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A B с observations This reaction is spontaneous only above 30. °C but proceeds at a slower rate below 199. °C. This reaction is spontaneous only below 19. °C. This reaction is exothermic and proceeds slower at temperatures below 60. °C. conclusions AH is AS is AH is AS is AH is AS is X (pick one) (pick one) (pick one) ✓ (pick one) (pick one) (pick one) Ś
Consider the oxidation of elemental cadmium (II) oxide. 2Cd(s)+O2 (g)--> 2CdO(s) Using the following thermochemical data, calculate the minimu temperature in degrees Celsius at which this reaction is spontaneous. Species delta Hf degrees (kJ/mol) S degrees (J/molxK) Cd(s) 0 51.8 O2 0 205.2 CdO(s) -258.4 54.8 Select the correct answer: a. 2594 degrees Celsius b. 2321 degrees Celsius c. 1.278 degrees Celsius d. -271.9 degrees Celsius e. -270.6 degrees Celsius
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A C observations This reaction is slower below 18. °C than above. This reaction is spontaneous only above 97. °C. This reaction is always spontaneous, but proceeds faster at temperatures above 72. °C. AH is AS is conclusions AH is AS is AH is AS is ✓ (pick one) positive negative unknown (pick one) (pick one) (pick one) (pick one)
The following reaction is endothermic. 2NH3(g) → N2(g) + 3H2(g) This means the reaction A. will be spontaneous at high temperatures. B. will be spontaneous at low temperatures. C. is not spontaneous at any temperature. D. is spontaneous at all temperatures.
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction A B с observations Crystallization of a pure compound is spontaneous only below 23. °C. This reaction is spontaneous only above 31. °C but proceeds at a faster rate above 83. °C. The reverse of this reaction is always spontaneous but proceeds faster at temperatures above 108. °C. AH is AS is AH is AS is conclusions ΔΗ is AS is (pick one) (pick one) (pick one) (pick one) (pick one) (pick one) V
Read the descriptions of physical or chemical changes in the table below. Then decide whether the change will be spontaneous, if you can. Change During an endothermic chemical reaction, four moles of gaseous reactants are turned into two moles of gaseous products. A solid precipitates from a solution, releasing heat as it does so. A solid absorbs heat and turns to a gas. Is this change spontaneous? Yes. O No. O Can't decide with information given. O Yes. O No. O Can't decide with information given. O Yes. O No. O Can't decide with information given.
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions AH is A This reaction is always spontaneous, but proceeds slower at temperatures below 45. °C. AS is ΔΗ is This reaction is spontaneous only above 150. °C but proceeds at a faster rate above 180. °C. AS is ΔΗ is This reaction is exothermic and proceeds slower at temperatures below 67. °C. AS is X C (pick one) (pick one) (pick one) (pick one) ✓ (pick one) (pick one) Ś ?
Consider the reaction below for the decomposition of carbon tetrachloride gas: CCl4(g) ------> C(s) + 2Cl2 (g) ΔH = + 95.7 kJ; ΔS = + 142.2 J/K If the reaction above is not spontaneous at 25 oC, determine at what temperature (if any) the reaction becomes spontaneous.