Use the attached data to plot a graph "ln a as a function of time" for both 20ºC and 30ºC. Use the equation: y=-mx +b where y is ln a, m is k, x is time. Does this poor confirm a first order reaction? If so, how do you know?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Use the attached data to plot a graph "ln a as a function of time" for both 20ºC and 30ºC. Use the equation: y=-mx +b where y is ln a, m is k, x is time. Does this poor confirm a first order reaction? If so, how do you know?

Time Elapsed Gas Buret
(min)
20°C :
0
5
10
15
20
25
30
35
40
00
30°C:
0
5
10
15
20
25
30
35
40
00
Reading (mL)
8
Vol 0₂ (in mL; (V-V) × (a) V. - V
H₂O-corrected -
reading)
10.81
10.54 37.71
15.01
14.63
19.28
18.80
22.47 21.91.
25.05
25.69
28.38
30.58
27.67
29.82
32.56 31.75
34.37
33.51
49.49 48.25
12.80
12.48
21.02 20.49
27.33
26.65
31.90
35.45
37.89 36.94
39.8061
33062
29.45
26.34
40.01
41.68
40.64
42-83
41.76
48.39 47.18
23.20
20.58
18.43
16.50
14.74
O
+=/ª
V-V. (2)
10.24
8.17
31.10
16.08
34.56 12.62 0.3637
6.54
5.47
O
In
a
34.70 1.0000
26.69 0.7692 -0.2624
20.53
0.5916
-0.5250
(₂₂)
a
k (min-¹)
1.0000
O
0.8915 -0.1149.
0.7810 -0.2472
0.6985 -0.3588 0.02392
0.615204858 0.02429
0.5457 -0.6057 0.02423
0.4887 -0.7160 002387
0.4376 -0.8265 0.02361
0.3909 -0.9393 0.02348
0.39
from Eq.[3-4]
Kaverge = 0.024min
0.4634 -0-7692 0.05128
0.3637 -1.0114 0.05057
0.2951 -1.2204 0.04882
0.2354 -1.4465 0.04822
0.1885 -1.6687 0.04768
0.1562 -1.89566 0.04642
Kaverage
O
=0.049 min
Transcribed Image Text:Time Elapsed Gas Buret (min) 20°C : 0 5 10 15 20 25 30 35 40 00 30°C: 0 5 10 15 20 25 30 35 40 00 Reading (mL) 8 Vol 0₂ (in mL; (V-V) × (a) V. - V H₂O-corrected - reading) 10.81 10.54 37.71 15.01 14.63 19.28 18.80 22.47 21.91. 25.05 25.69 28.38 30.58 27.67 29.82 32.56 31.75 34.37 33.51 49.49 48.25 12.80 12.48 21.02 20.49 27.33 26.65 31.90 35.45 37.89 36.94 39.8061 33062 29.45 26.34 40.01 41.68 40.64 42-83 41.76 48.39 47.18 23.20 20.58 18.43 16.50 14.74 O +=/ª V-V. (2) 10.24 8.17 31.10 16.08 34.56 12.62 0.3637 6.54 5.47 O In a 34.70 1.0000 26.69 0.7692 -0.2624 20.53 0.5916 -0.5250 (₂₂) a k (min-¹) 1.0000 O 0.8915 -0.1149. 0.7810 -0.2472 0.6985 -0.3588 0.02392 0.615204858 0.02429 0.5457 -0.6057 0.02423 0.4887 -0.7160 002387 0.4376 -0.8265 0.02361 0.3909 -0.9393 0.02348 0.39 from Eq.[3-4] Kaverge = 0.024min 0.4634 -0-7692 0.05128 0.3637 -1.0114 0.05057 0.2951 -1.2204 0.04882 0.2354 -1.4465 0.04822 0.1885 -1.6687 0.04768 0.1562 -1.89566 0.04642 Kaverage O =0.049 min
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