The reaction between bromate ions and bromide ions in acidic aqueous solution is given by the following equation: BrO3- (aq) + 5Br- (aq) + 6H+ (aq) --> 3Br2 (l) + 3H2O (l) The experimental results are given below. Experiment Initial  [BrO3-] Initial  [Br-] Initial  [H+] Initial Rate  (M s-1) 1 0.10 0.10 0.10 8.0 x 10-4 2 0.20 0.10 0.10 1.6 x 10-3 3 0.20 0.20 0.10 3.2 x 10-3 4 0.10 0.10 0.20 3.2 x 10-3 Using these data, determine the orders for all reactants, the overall reaction order, and the value of the rate constant.

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The reaction between bromate ions and bromide ions in acidic aqueous solution is given by the following equation:

BrO3- (aq) + 5Br- (aq) + 6H+ (aq) --> 3Br2 (l) + 3H2O (l)

The experimental results are given below.

Experiment

Initial  [BrO3-]

Initial  [Br-]

Initial  [H+]

Initial Rate  (M s-1)

1

0.10

0.10

0.10

8.0 x 10-4

2

0.20

0.10

0.10

1.6 x 10-3

3

0.20

0.20

0.10

3.2 x 10-3

4

0.10

0.10

0.20

3.2 x 10-3

Using these data, determine the orders for all reactants, the overall reaction order, and the value of the rate constant.

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