Use Table 1 to determine if the followingequilibria will move left or righti. HF (aq) + NH3 (aq) = F¯ (aq) + NH4 + (aq)ii. HCO3¯ (aq) + SO4²- (aq) =CO3²- (aq) +HSO4 (aq)table 1. Relative strengths for some conjugateacid-base pairs:ACIDBASE100%ionized inH₂OAcid strength increasesStrongWeakHCICITH₂SO4HSO4HNO3NO3H3O+ (aq)H₂OHSO4SO₂²-H3PO4H₂PO4HFF™HC₂H30₂C₂H₂O₂H₂CO3HCO3HSH₂SH₂PO4 HPO4²-NH4+NH3HCO3HPO ²-CO3²-PO4³-H₂OOH™OH0²-H₂H™CH4CH3NegligibleBase strength increasesWeakStrong100%protonatedin H₂O b. How many grams of NH4Cl are needed tomake 0.75 Make an NH4Cl (aq) solution at pH5.00? (Kb = 1.8 × 10-5 for NH3)c. The osmotic pressure of a 0.100 M HA (aq)solution at 25.0 °C is 2.57 atm. Calculate:i. acid constant, Ka, to the monoprotic acid HA.ii. the base constant, Kb, to the conjugate baseof HA.

To predict the direction of equilibrium in the given acid -base reaction. "Since you have asked…

Answered: Use Table 1 to determine if the…

Use Table 1 to determine if the following equilibria will move left or right i. HF (aq) + NH3 (aq) = F¯ (aq) + NH4 + (aq) ii. HCO3¯ (aq) + SO4²- (aq) =CO3²- (aq) + HSO4 (aq)

World of Chemistry, 3rd edition

3rd Edition

ISBN:9781133109655

Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste

Chapter16: Acids And Bases

Section: Chapter Questions

Problem 15A

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For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.
Are solutions of the following salts acidic, basic, or neutral? For those that are not neutral, write balanced equations for the reactions causing the solution to be acidic or basic. The relevant Ka, and Kb values are found in Tables 13-2 and 13-3. a. Sr(NO3)2 b. NH4C2H3O2 c. CH3NH3Cl d. C6H5NH3ClO2 e. NH4F f. CH3NH3CN
In the following net ionic reaction, identify each species as either a Brnsted-Lowry acid or a Brnsted -Lowry base: CH3COO(aq)+HS(aq)CH3COOH(aq)+S2(aq). Identify the conjugate of each reactant and state whether it is a conjugate acid or a conjugate base.
Write the formula and name for the conjugate acid of the following substances. (The information in Tables 15.6 and 15.8 may be helpful.) (a) N2H4 (b) NO2 (c) ClO4 (d) I
Pure liquid ammonia ionizes in a manner similar to that of water. (a) Write the equilibrium for the autoionization of liquid ammonia. (b) Identify the conjugate acid form and the base form of the solvent. (c) Is NaNH2 an acid or a base in this solvent? (d) Is ammonium bromide an acid or a base in this solvent?
Aqueous Solutions of Acids, Bases, and Salts a For each of the following salts, write the reaction that occurs when it dissociates in water: NaCl(s), NaCN(s), KClO2(s), NH4NO3(s), KBr(aq), and NaF(s). b Consider each of the reactions that you wrote above, and identify the aqueous ions that could be proton donors (acids) or proton acceptors (bases). Briefly explain how you decided which ions to choose. c For each of the acids and bases that you identified in pan b, write the chemical reaction it can undergo in aqueous solution (its reaction with water). d Are there any reactions that you have written above that you anticipate will occur to such an extent that the pH of the solution will be affected? As pan of your answer, be sure to explain how you decided. e Assume that in each case above, 0.01 mol of the salt was dissolved in enough water at 25C to make 1.0 L of solution. In each case what additional information would you need in order to calculate the pH? If there are cases where no additional information is required, be sure to state that as well. f Say you take 0.01 mol of NH4CN and dissolve it in enough water at 25C to make 1.0 L of solution. Using chemical reactions and words, explain how you would go about determining what effect this salt will have on the pH of the solution. Be sure to list any additional information you would need to arrive at an answer.
Boron trifluoride, BF3, and diethyl ether, (C2H5)2O, react to produce a compound with the formula BF3 : (C2H5)2O. A coordinate covalent bond is formed between the boron atom on BF3 and the oxygen atom on (C2H5)2O. Write the equation for this reaction, using Lewis electron-dot formulas. Label the Lewis acid and the Lewis base. Determine how many grams of BF3: (C2H5)2O are formed when 9.10 g BF3 and 23.3 g (C2H5)2O are placed in a reaction vessel, assuming that the reaction goes to completion.
. The concepts of acid-base equilibria were developed in this chapter for aqueous solutions (in aqueous solutions, water is the solvent and is intimately involved in the equilibria). However, the Brønsted-Lowry acid-base theory can be extended easily to other solvents. One such solvent that has been investigated in depth is liquid ammonia. NH3. a. Write a chemical equation indicating how HCl behaves as an acid in liquid ammonia. b. Write a chemical equation indicating how OH- behaves as a base in liquid ammonia.
To measure the relative strengths of bases stronger than OH, it is necessary to choose a solvent that is a weaker acid than water. One such solvent is liquid ammonia. (a) Write a chemical equation for the autoionization of ammonia. (b) What is the strongest acid and base that can exist in liquid ammonia? (c) Will a solution of HCI in liquid ammonia be a strong electrical conductor, a weak conductor, or a nonconductor? (d) Oxide ion (O2) is a stronger base than the amide ion (NH2). Write an equation for the reaction of O2 with NH3 in liquid ammonia. Will the equilibrium favor products or reactants?
Using the diagrams shown in Problem 10-37, which of the four acids is the weakest acid?
Ionization of the first proton from H2SO4 is complete (H2SO4 is a strong acid); the acid-ionization constant for the second proton is 1.1 102. a What would be the approximate hydronium-ion concentration in 0.100 M H2SO4 if ionization of the second proton were ignored? b The ionization of the second proton must be considered for a more exact answer, however. Calculate the hydronium-ion concentration in 0.100 M H2SO4, accounting for the ionization of both protons.
(a) Which is the stronger Bronsted acid, HCO3 or NH4+? Which has the stronger conjugate base? (b) Is a reaction between HCO3- ions and NH3 product- or reactant-favored at equilibrium? HCO3(aq) + NH3(aq) CO32(aq) + NH4+(aq) (c) You mix solutions of sodium hydrogen phosphate and ammonia. The net ionic equation for a possible reaction is HPO42(aq) + NH3(aq) PO43(aq) + NH4+(aq) Does the equilibrium lie to the left or to the right for this reaction?