Use bond energies from the table to estimate ΔrH for the following reaction. C2H2(g)+H2(g)→C2H4(g)      ΔrH=? Express the answer in kJ/mol to three significant figures.

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Use bond energies from the table to estimate ΔrH for the following reaction.

C2H2(g)+H2(g)→C2H4(g)      ΔrH=?

Express the answer in kJ/mol to three significant figures.
 
TABLE 10.3 Some Average Bond Energiesa
Bond Energy,
kJ mol-1
Bond Energy,
kJ mol-1
Bond Energy,
kJ mol-1
Bond
Bond
Bond
H-H
436
C-C
347
N-N
163
H-C
414
C=C
C=C
611
N=N
N=N
418
H-N
389
837
946
H-0
H-S
N-O
N=0
464
C-N
305
222
368
C=N
615
590
H-F
565
C=N
891
0-0
142
H-Cl
431
360
0=0
498
Н-Br
364
736b
F-F
159
H-I
297
C-CI
339
Cl-Ci
243
Br-Br
193
I-I
151
*Although all data are listed with about the same precision (three significant figures), some
values are actually known more precisely. Specifically, the values for the diatomic mole-
cules H2, HF, HCÍ, HBr, HI, N2 (Ñ=N), O2 (0=0), F2, Cl2, Br2, and I2 are actually
bond-dissociation energies, rather than average bond energies.
ÞThe value for the C=O bonds in CO2 is 799 kJ mol-!.
You may want to reference (Page) Section 10.1 while completing this problem.
Transcribed Image Text:TABLE 10.3 Some Average Bond Energiesa Bond Energy, kJ mol-1 Bond Energy, kJ mol-1 Bond Energy, kJ mol-1 Bond Bond Bond H-H 436 C-C 347 N-N 163 H-C 414 C=C C=C 611 N=N N=N 418 H-N 389 837 946 H-0 H-S N-O N=0 464 C-N 305 222 368 C=N 615 590 H-F 565 C=N 891 0-0 142 H-Cl 431 360 0=0 498 Н-Br 364 736b F-F 159 H-I 297 C-CI 339 Cl-Ci 243 Br-Br 193 I-I 151 *Although all data are listed with about the same precision (three significant figures), some values are actually known more precisely. Specifically, the values for the diatomic mole- cules H2, HF, HCÍ, HBr, HI, N2 (Ñ=N), O2 (0=0), F2, Cl2, Br2, and I2 are actually bond-dissociation energies, rather than average bond energies. ÞThe value for the C=O bonds in CO2 is 799 kJ mol-!. You may want to reference (Page) Section 10.1 while completing this problem.
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