Type numbers in the boxes. 45.0 mL of o.650 M HNO, is titrated by o.650 M KOH. aby Part 1: 10 points Calculate the pH of the acid solution before any titrant is aby Part 2: 10 points added. aby Part 3: 1 points pH = aby Part 4: 10 points Calculate the pH after 1.47 mL of o.650 M KOH is added 31 points to 45.0 mL of 0.650 M HNO,. pH = Calculate the pH after 45.00 mL of o.650 M KOH is added to 45.0 mL of 0.650 ΜΗΝΟ. pH = Calculate the pH after 89.5 mL of o.650 M KOH is added to 45.0 mL of 0.650 M HNO,. pH =

Type numbers in the boxes. 45.0 mL of o.650 M HNO, is titrated by o.650 M KOH. aby Part 1: 10 points Calculate the pH of the acid solution before any titrant is aby Part 2: 10 points added. aby Part 3: 1 points pH = aby Part 4: 10 points Calculate the pH after 1.47 mL of o.650 M KOH is added 31 points to 45.0 mL of 0.650 M HNO,. pH = Calculate the pH after 45.00 mL of o.650 M KOH is added to 45.0 mL of 0.650 ΜΗΝΟ. pH = Calculate the pH after 89.5 mL of o.650 M KOH is added to 45.0 mL of 0.650 M HNO,. pH =

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter14: Acids And Bases

Section: Chapter Questions

Problem 4ALQ: Consider a solution prepared by mixing a weak acid HA and HCl. What are the major species? Explain...

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Similar questions

Mixing together solutions of acetic acid and sodium hydroxide can make a buffered solution. Explain. How does the amount of each solution added change the effectiveness of the buffer?
You have a solution of the weak acid HA and add some HCl to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
A buffer is prepared in which the ratio [ H2PO4 ]/[ HPO42 ]is 3.0. (a) What is the pH of this buffer? (b) Enough strong acid is added to convert 15% of HPO42- to H2PO4-. What is the pH of the resulting solution? (c) Enough strong base is added to make the pH 7.00. What is the ratio of [H2PO4-] to [HPO42-] at this point?
Follow the directions of Question 64. Consider two beakers: Beaker A has a weak acid(K a=1105). Beaker B has HCI. The volume and molarity of each acid in the beakers are the same. Both acids are to be titrated with a 0.1 M solution of NaOH. (a) Before titration starts (at zero time), the pH of the solution in Beaker A is the pH of the solution in Beaker B. (b) At half-neutralization (halfway to the equivalence point), the pH of the solution in Beaker A the pH of the solution in Beaker B. (c) When each solution has reached its equivalence point, the pH of the solution in Beaker A the pH of the solution in Beaker B. (d) At the equivalence point, the volume of NaOH used to titrate HCI in Beaker B the volume of NaOH used to titrate the weak acid in Beaker A.
A friend asks the following: Consider a buffered solution made up of the weak acid HA and its salt NaA. If a strong base like NaOH is added, the HA reacts with the OH to form A. Thus the amount of acid (HA) is decreased, and the amount of base (A) is increased. Analogously, adding HCI to the buffered solution forms more of the acid (HA) by reacting with the base (A). Thus how can we claim that a buffered solution resists changes in the pH of the solution? How would you explain buffering to this friend?
Another way to treat data from a pH titration is to graph the absolute value of the change in pH per change in milliliters added versus milliliters added (pH/mL versus mL added). Make this graph using your results from Exercise 61. What advantage might this method have over the traditional method for treating titration data?
Define a buffer solution. What makes up a buffer solution? How do buffers absorb added H+ or OH with little pH change? Is it necessary that the concentrations of the weak acid and the weak base in a buffered solution be equal? Explain. What is the pH of a buffer when the weak acid and conjugate base concentrations are equal? A buffer generally contains a weak acid and its weak conjugate base, or a weak base and its weak conjugate acid, in water. You can solve for the pH by setting up the equilibrium problem using the K.a reaction of the weak acid or the Kb reaction of the conjugate base. Both reactions give the same answer for the pH of the solution. Explain. A third method that can be used to solve for the pH of a buffet solution is the HendersonHasselbalch equation. What is the HendersonHasselbalch equation? What assumptions are made when using this equation?
Consider the nanoscale-level representations for Question 111 of the titration of the aqueous strong acid HA with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: (a) After a very small volume of titrant has been added to the initial HA solution? (b) Halfway to the equivalence point? (c) When enough titrant has been added to take the solution just past the equivalence point? (d) At the equivalence point? Nanoscale representations for Question 111.
The titration of Na2CO3 with HCl bas the following qualitative profile: a. Identify the major species in solution at points AF. b. Calculate the pH at the halfway points to equivalence, B and D. (Hint: Refer to Exercise 113.)
A quantity of 0.15 M hydrochloric acid is added to a solution containing 0.10 mol of sodium acetate. Some of the sodium acetate is converted to acetic acid, resulting in a final volume of 650 mL of solution. The pH of the final solution is 4.56. a What is the molar concentration of the acetic acid? b How many milliliters of hydrochloric acid were added to the original solution? c What was the original concentration of the sodium acetate?
. Which component of a buffered solution is capable of combining with an added strong acid? Using your example from Exercise 60, show how this component would react with added HC1.