Two palladium complexes A and B are prepared by the following reactions: K2[PdCl4] + 2 NH3 → A + side products [Pd(NH3)4](NO3)2+ 2 KC1 → B + side products The molecular formula of A and B are the same. A is soluble in polar solvents while B is soluble in non-polar solvents. Draw the structures of A and B, assign the point group symmetry of each complex, and explain the observed solubilities based on the point group symmetries.

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Two palladium complexes A and B are prepared by the following reactions:
K2[PdCl4] + 2 NH3 → A + side products
[Pd(NH3)4](NO3)2+ 2 KC1 → B + side products
The molecular formula of A and B are the same. A is soluble in polar solvents while
B is soluble in non-polar solvents.
Draw the structures of A and B, assign the point group symmetry of each complex, and
explain the observed solubilities based on the point group symmetries.
Transcribed Image Text:Two palladium complexes A and B are prepared by the following reactions: K2[PdCl4] + 2 NH3 → A + side products [Pd(NH3)4](NO3)2+ 2 KC1 → B + side products The molecular formula of A and B are the same. A is soluble in polar solvents while B is soluble in non-polar solvents. Draw the structures of A and B, assign the point group symmetry of each complex, and explain the observed solubilities based on the point group symmetries.
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