Two cycloaddition reactions (I and II) are shown below. Which of the options given below best describes reactions I and II? CN I) CN CN II) CN CN CN CN "CN A. Reaction I is allowed and has a Huckel transition state; Reaction II is forbidden and has a Mobius transition state. B. Reaction I is allowed and has a Mobius transition state. Reaction II is forbidden and has a Huckel transition state. C. Reaction I is forbidden and has a Huckel transition state. Reaction II is allowed and has a Mobius transition state. D. Reaction I is forbidden and has a Mobius transition state. Reaction II is allowed and has a Huckel transition state. Option A Option B O Option C O Option D

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 34AP: Bicyclohexadiene, also known as Dewar benzene, is extremely stable despite the fact that its...
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Two cycloaddition reactions (I and II) are shown below. Which of the options given below
best describes reactions I and II?
CN
I)
CN
CN
II)
CN
CN
CN
CN
"CN
A. Reaction I is allowed and has a Huckel transition state; Reaction II is forbidden and has a
Mobius transition state.
B. Reaction I is allowed and has a Mobius transition state. Reaction II is forbidden and has a
Huckel transition state.
C. Reaction I is forbidden and has a Huckel transition state. Reaction II is allowed and has a
Mobius transition state.
D. Reaction I is forbidden and has a Mobius transition state. Reaction II is allowed and has a
Huckel transition state.
Option A
Option B
O Option C
O Option D
Transcribed Image Text:Two cycloaddition reactions (I and II) are shown below. Which of the options given below best describes reactions I and II? CN I) CN CN II) CN CN CN CN "CN A. Reaction I is allowed and has a Huckel transition state; Reaction II is forbidden and has a Mobius transition state. B. Reaction I is allowed and has a Mobius transition state. Reaction II is forbidden and has a Huckel transition state. C. Reaction I is forbidden and has a Huckel transition state. Reaction II is allowed and has a Mobius transition state. D. Reaction I is forbidden and has a Mobius transition state. Reaction II is allowed and has a Huckel transition state. Option A Option B O Option C O Option D
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