Tooth enamel is composed of hydroxyapatite, whose simplestformula is Ca5(PO4)3OH, and whose correspondingKsp = 6.8 x 10-27. As discussed in the Chemistry and Lifebox on page 746, fluoride in fluorinated water or in toothpastereacts with hydroxyapatite to form fluoroapatite,Ca5(PO4)3F, whose Ksp = 1.0 x 10-60. (a) Write the expressionfor the solubility-constant for hydroxyapatite andfor fluoroapatite. (b) Calculate the molar solubility of eachof these compounds.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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Tooth enamel is composed of hydroxyapatite, whose simplest
formula is Ca5(PO4)3OH, and whose corresponding
Ksp = 6.8 x 10-27. As discussed in the Chemistry and Life
box on page 746, fluoride in fluorinated water or in toothpaste
reacts with hydroxyapatite to form fluoroapatite,
Ca5(PO4)3F, whose Ksp = 1.0 x 10-60. (a) Write the expression
for the solubility-constant for hydroxyapatite and
for fluoroapatite. (b) Calculate the molar solubility of each
of these compounds.

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