Titration A, endpoint pH= = Titration B, endpoint pH= = 2. pka or pKs = 3. Ka or Kb:

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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TITRATION A
_Hel titrated with NaOH
4.
Volume of second
reagent added (mL)
0.0
5.0
10.0
15.0
20.0
21.0
22.0
23,0
24.0
25.0
26.0
27.0
28.0
29.0
30.0
35.0
40.0
45.0
50.0
pH
si
1.66
1.82
2.01
2.23
2.39
2.61
3.03
10.52
11.36
11.65
11.81
11.92
22-01
12.23
12.38
12.42
12.54
ANSWERS TO QUESTIONS
1. Titration A, endpoint pH:
Titration B, endpoint pH=
=
Why no K asked for Titration A?
TITRATION B
CH3 Cold titrated with _Naoh
Volume of second
reagent added (mL)
0.0
5.0
10.0
15.0
20.0
21.0
22.0
23.0
24.0
25.0
26.0
27.0
28.0
29.0
30.0
35.0
40.0
45.0
50.0
2. pk₁ or pK,
3. Ka or Kb-
=
pH
3.15
4.11
4.56
4.88
5.33
5.37
5.45
5.52
5.69
6.05
6.55
6.85
10.04
11.30
11.56
12.05
12.25
12.35
12.43
Transcribed Image Text:TITRATION A _Hel titrated with NaOH 4. Volume of second reagent added (mL) 0.0 5.0 10.0 15.0 20.0 21.0 22.0 23,0 24.0 25.0 26.0 27.0 28.0 29.0 30.0 35.0 40.0 45.0 50.0 pH si 1.66 1.82 2.01 2.23 2.39 2.61 3.03 10.52 11.36 11.65 11.81 11.92 22-01 12.23 12.38 12.42 12.54 ANSWERS TO QUESTIONS 1. Titration A, endpoint pH: Titration B, endpoint pH= = Why no K asked for Titration A? TITRATION B CH3 Cold titrated with _Naoh Volume of second reagent added (mL) 0.0 5.0 10.0 15.0 20.0 21.0 22.0 23.0 24.0 25.0 26.0 27.0 28.0 29.0 30.0 35.0 40.0 45.0 50.0 2. pk₁ or pK, 3. Ka or Kb- = pH 3.15 4.11 4.56 4.88 5.33 5.37 5.45 5.52 5.69 6.05 6.55 6.85 10.04 11.30 11.56 12.05 12.25 12.35 12.43
Experiment 9.B
ACID-BASE TITRATION USING THE PH METER
Acids and bases react together to produce a salt and water. This reaction is called neutralization. The general
form of the reaction is the following:
HA + BOH →→→→→ B*A¯ + H₂O
Some specific examples are shown below:
HCI + NaOH → Naci + H₂O
HC] + NH4OH → NH4Cl + H₂O
HC₂H3O₂ + KOH
→ KC₂H₂O₂ + H₂O
→ NHÂNO3 + H₂O
HCHO, + NaOH
→ NaCHO₂ + H₂O
Titration is a method of very accurately determining the amount of one reagent needed to react with
another reagent. If these reagents are liquid, for example solutions of acid or base, then it is convenient to
measure the amounts by volume. Such a titration is called a volumetric titration.
HNO3 + NH4OH
One method of following the progress of an acid-base titration is by measuring the concentration of H*
or H3O* in the reaction flask. If a base is in the flask there will initially be a very low [H3O*]. As acid is added
to neutralize the base, the [H3O*]. increases. Just the opposite situation occurs if the flask initially contains
acid and base is being added.
The [H3O*] can be measured using a pH-meter, where pH is defined:
pH = -logio[H3O¹].
Therefore bases have high pH (low [H3O*]) and acids have low pH (high [H3O*]).
Transcribed Image Text:Experiment 9.B ACID-BASE TITRATION USING THE PH METER Acids and bases react together to produce a salt and water. This reaction is called neutralization. The general form of the reaction is the following: HA + BOH →→→→→ B*A¯ + H₂O Some specific examples are shown below: HCI + NaOH → Naci + H₂O HC] + NH4OH → NH4Cl + H₂O HC₂H3O₂ + KOH → KC₂H₂O₂ + H₂O → NHÂNO3 + H₂O HCHO, + NaOH → NaCHO₂ + H₂O Titration is a method of very accurately determining the amount of one reagent needed to react with another reagent. If these reagents are liquid, for example solutions of acid or base, then it is convenient to measure the amounts by volume. Such a titration is called a volumetric titration. HNO3 + NH4OH One method of following the progress of an acid-base titration is by measuring the concentration of H* or H3O* in the reaction flask. If a base is in the flask there will initially be a very low [H3O*]. As acid is added to neutralize the base, the [H3O*]. increases. Just the opposite situation occurs if the flask initially contains acid and base is being added. The [H3O*] can be measured using a pH-meter, where pH is defined: pH = -logio[H3O¹]. Therefore bases have high pH (low [H3O*]) and acids have low pH (high [H3O*]).
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