Over much of the titration curve, the pH lies within 1 pH unit of the pk- In this range, the change in pH with moles of base added is minimal. 13 12 11 10 9 8 7 4 3 2 1 0 NH HCOOH NH3 pk of NH HCOO pk of HCOOH 25 5 75 Moles base added per mole acid Titration curves of weak acids. 1.0 At the midpoint of the titration where half the acid is neutralized, pH=pKa Part A Calculate the pH of a 1.0 M NH4Cl solution. (Ka for NH4+ is 5.62 × 10-10) Express your answer to two decimal places. pH = Submit Part B pH = Submit 195| ΑΣΦ Calculate the pH of the solution that results following addition of 10 mL of 1.0 M NaOH to 50 mL of 1.0 M NH₂ Cl. Express your answer to two decimal places. Part C Request Answer 15. ΑΣΦ ? Request Answer ? Calculate the pH of the solution that results following addition of 21 mL of 1.0 M NaOH to 50 mL of 1.0 M NH₂ Cl. Express your answer to two decimal places.

Chemistry
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Over much of
the titration
curve, the pH
lies within 1 pH
unit of the pka.
In this range,
the change in
pH with moles
of base added
is minimal.
13
12
11
10
9
8
7
6
TO
4
3
2
1
0
NH
HCOOH
NH3
pk of NH4
HCOO
pk of HCOOH
.5
25
.75
Moles base added per mole acid
Titration curves of weak acids.
1.0
At the midpoint
of the titration
where half the
acid is
neutralized,
pH=pKa
Part A
Calculate the pH of a 1.0 M NH4Cl solution. (Ką for NH4+ is
5.62 × 10-10)
Express your answer to two decimal places.
pH =
Submit
Part B
pH =
Submit
VO ΑΣΦ
Calculate the pH of the solution that results following addition of 10 mL
of 1.0 M NaOH to 50 mL of 1.0 M NH₂ Cl.
Express your answer to two decimal places.
Part C
Request Answer
5 ΑΣΦ
?
Request Answer
?
Calculate the pH of the solution that results following addition of 21 mL
of 1.0 M NaOH to 50 mL of 1.0 M NH₂ Cl.
Express your answer to two decimal places.
Transcribed Image Text:Over much of the titration curve, the pH lies within 1 pH unit of the pka. In this range, the change in pH with moles of base added is minimal. 13 12 11 10 9 8 7 6 TO 4 3 2 1 0 NH HCOOH NH3 pk of NH4 HCOO pk of HCOOH .5 25 .75 Moles base added per mole acid Titration curves of weak acids. 1.0 At the midpoint of the titration where half the acid is neutralized, pH=pKa Part A Calculate the pH of a 1.0 M NH4Cl solution. (Ką for NH4+ is 5.62 × 10-10) Express your answer to two decimal places. pH = Submit Part B pH = Submit VO ΑΣΦ Calculate the pH of the solution that results following addition of 10 mL of 1.0 M NaOH to 50 mL of 1.0 M NH₂ Cl. Express your answer to two decimal places. Part C Request Answer 5 ΑΣΦ ? Request Answer ? Calculate the pH of the solution that results following addition of 21 mL of 1.0 M NaOH to 50 mL of 1.0 M NH₂ Cl. Express your answer to two decimal places.
Expert Solution
Step 1: Given

Given:

Part A:

Concentration of NH4Cl = space 1.0 space straight M

straight K subscript straight a space of space NH subscript 4 superscript plus equals 5.62 cross times 10 to the power of negative 10 end exponent

Part B:

For NH4Cl:

table row cell Concentration space end cell equals cell space 1.0 space straight M space end cell row cell Volume space end cell equals cell space 50 space mL end cell end table

For NaOH:

Concentration space equals space 1.0 space straight M
space Volume space equals space 10 space mL

Part C:

For NH4Cl:

table row cell space Concentration space end cell equals cell space 1.0 space straight M space end cell row cell Volume space end cell equals cell space 50 space mL end cell end table

For NOH:

table row cell Concentration space end cell equals cell space 1.0 space straight M space end cell row cell Volume space end cell equals cell space 21 space mL end cell end table


The pH of a solution is determined using the negative logarithm of the hydrogen ion concentration (H+). The pH of a solution is a measure of its acidity or alkalinity on a logarithmic scale ranging from 0 to 14.

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