Chemical Principles in the Laboratory
11th Edition
ISBN:9781305264434
Author:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher:Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Chapter25: Ph Measurements-buffers And Their Properties
Section: Chapter Questions
Problem 1ASA
Related questions
Question
Titration A |
|
HCl Titrated with NaOH |
|
Volume of NaOH |
pH |
0.0 |
1.00 |
5.0 |
1.18 |
10.0 |
1.37 |
15.0 |
1.60 |
20.0 |
1.95 |
21.0 |
2.06 |
22.0 |
2.19 |
23.0 |
2.38 |
24.0 |
2.69 |
25.0 |
7.00 |
26.0 |
11.29 |
27.0 |
11.58 |
28.0 |
11.76 |
29.0 |
11.87 |
30.0 |
11.96 |
35.0 |
12.22 |
40.0 |
12.36 |
45.0 |
12.46 |
50.0 |
12.52 |
Titration B |
|
HC2H3O2 Titrated with NaOH |
|
Volume of NaOH |
pH |
0.0 |
2.87 |
5.0 |
4.14 |
10.0 |
4.56 |
15.0 |
4.92 |
20.0 |
5.34 |
21.0 |
5.46 |
22.0 |
5.61 |
23.0 |
5.80 |
24.0 |
6.12 |
25.0 |
8.87 |
26.0 |
11.30 |
27.0 |
11.56 |
28.0 |
11.75 |
29.0 |
11.87 |
30.0 |
11.96 |
35.0 |
12.22 |
40.0 |
12.36 |
45.0 |
12.46 |
50.0 |
12.52 |
1. Titration A, endpoint pH =
Titration B, endpoint pH =
2. pKa or pKb =
3. Ka or Kb =
4. Why no K asked for Titration A?
5. Write the value of pKa and Ka that you determined from your graph.
6. If the actual pKa was 4.718, determine the percent error. If the actual Ka was 1.815x10-5, determine the percent error.
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