Three liquid samples of known masses are heated to their boiling points with the use of a heater rated at 475.0 W. Once the boiling points of each sample are reached, the samples are heated for an additional 4.60 min, which results in the vaporization of some of each sample. After 4.60 min, the samples are cooled and the masses of the remaining liquids are determined. The process is performed at constant pressure. The results are recorded in the table. Liquid Boiling point ("C) Initial mass (g) Final mass (g) 441.0 331.00 CH,OH 64.5 462.0 106.37 36.1 C,H2 CH 80.1 615.5 312.51 Calculate the molar enthalpy of vaporization, AH. and the molar entropy of vaporization, ASp, for each sample. Assume that all of the heat from the heater goes into the sample. kJ
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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