þetermine the values of AH', AS'and AG'for the following two reactions at 25 °C, using the data given in the table. Indicate if each of reactions is spontaneous or not Substance AH, (kJ/mol) S° (J/Kmol) AG (kJ/mol) H(g) 131 N2(9) NH,(g) 192 -46 193 -17 So,(g) -396 257 -371 H,0(1) -286 70 -237 H,SO,(aq) -909 20 -745 a. 3 H2(g) + N2 (g)-2 NH3(g) b. SO,(g) + H20(1) H,SO,(aq)
þetermine the values of AH', AS'and AG'for the following two reactions at 25 °C, using the data given in the table. Indicate if each of reactions is spontaneous or not Substance AH, (kJ/mol) S° (J/Kmol) AG (kJ/mol) H(g) 131 N2(9) NH,(g) 192 -46 193 -17 So,(g) -396 257 -371 H,0(1) -286 70 -237 H,SO,(aq) -909 20 -745 a. 3 H2(g) + N2 (g)-2 NH3(g) b. SO,(g) + H20(1) H,SO,(aq)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Determine the Values of ΔHᵣ°, ΔS° and ΔGᵣ° for Chemical Reactions**
The following table provides thermodynamic data for several substances, which can be used to calculate the standard enthalpy change (ΔHᵣ°), standard entropy change (ΔS°), and standard Gibbs free energy change (ΔGᵣ°) for two chemical reactions at 25°C. The spontaneity of each reaction is also determined based on these values.
| Substance | ΔHᶠ° (kJ/mol) | S° (J/K∙mol) | ΔGᶠ° (kJ/mol) |
|-------------|---------------|--------------|---------------|
| H₂(g) | 0 | 131 | 0 |
| N₂(g) | 0 | 192 | 0 |
| NH₃(g) | -46 | 193 | -17 |
| SO₃(g) | -396 | 257 | -371 |
| H₂O(l) | -286 | 70 | -237 |
| H₂SO₄(aq) | -909 | 20 | -745 |
**Reactions:**
a. \( \text{3 H}_2(g) + \text{N}_2(g) \rightarrow \text{2 NH}_3(g) \)
b. \( \text{SO}_3(g) + \text{H}_2\text{O}(l) \rightarrow \text{H}_2\text{SO}_4(aq) \)
Use the data from the table to calculate the ΔHᵣ°, ΔS°, and ΔGᵣ° for each reaction, and determine if each reaction is spontaneous at 25°C.
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