There are two main typs of isotopes of Bromine in the nature, one is 79Br with the atomic mass of 79 amu, and another one is 8¹Br with the atomic mass of 81 amu. Assume both diatomic molecules, H7⁹Br and H8¹Br, behave as harmonic oscillators and rigid rotators. (a) The force constant (k) of H7⁹Br is 381 N/m. Calculate the fundamental vibrational frequency (v) of H7 Br. Report your value in Hz. (b) The rotational constant (B) of H¹Br is 10 cm¹¹. Assuming the two molecules have the same chemical bond length, calculate the rotational constant of H8¹Br. Report your value in cm³¹.

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### Isotopes of Bromine and Their Molecular Behavior

There are two main types of isotopes of Bromine in nature: one is \(^{79}\text{Br}\) with the atomic mass of 79 amu, and the other is \(^{81}\text{Br}\) with the atomic mass of 81 amu. Assume both diatomic molecules, H\(^{79}\text{Br}\) and H\(^{81}\text{Br}\), behave as harmonic oscillators and rigid rotators.

#### (a) Fundamental Vibrational Frequency

The force constant (\(k\)) of H\(^{79}\text{Br}\) is 381 N/m. Calculate the fundamental vibrational frequency (\(\nu\)) of H\(^{79}\text{Br}\). Report your value in Hz.

#### (b) Rotational Constant

The rotational constant (\(\tilde{B}\)) of H\(^{79}\text{Br}\) is 10 cm\(^{-1}\). Assuming the two molecules have the same chemical bond length, calculate the rotational constant of H\(^{81}\text{Br}\). Report your value in cm\(^{-1}\).
Transcribed Image Text:### Isotopes of Bromine and Their Molecular Behavior There are two main types of isotopes of Bromine in nature: one is \(^{79}\text{Br}\) with the atomic mass of 79 amu, and the other is \(^{81}\text{Br}\) with the atomic mass of 81 amu. Assume both diatomic molecules, H\(^{79}\text{Br}\) and H\(^{81}\text{Br}\), behave as harmonic oscillators and rigid rotators. #### (a) Fundamental Vibrational Frequency The force constant (\(k\)) of H\(^{79}\text{Br}\) is 381 N/m. Calculate the fundamental vibrational frequency (\(\nu\)) of H\(^{79}\text{Br}\). Report your value in Hz. #### (b) Rotational Constant The rotational constant (\(\tilde{B}\)) of H\(^{79}\text{Br}\) is 10 cm\(^{-1}\). Assuming the two molecules have the same chemical bond length, calculate the rotational constant of H\(^{81}\text{Br}\). Report your value in cm\(^{-1}\).
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