The vibrational contribution to the heat capacity is given by e-eV /2T Cm = R -e-eV/T Show that in the high temperature limit (when 0' « T) T. = R. (HINT: for small values of x, e* = 1+ x). Explain each step in your derivation.

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the vibrational contribution to the heat capacity is given by the photo below. show that in the high temperature limit C=R.(For small values of x, e^x=1+x)

The vibrational contribution to the heat capacity is given by
2
e-eV /2T
2
= R ()
Show that in the high temperature limit (when 0V « T)
%3D
v,m
(1-e-oV/T
= R. (HINT: for small values of x, e* = 1+ x). Explain each step in your derivation.
T-e-6%
Transcribed Image Text:The vibrational contribution to the heat capacity is given by 2 e-eV /2T 2 = R () Show that in the high temperature limit (when 0V « T) %3D v,m (1-e-oV/T = R. (HINT: for small values of x, e* = 1+ x). Explain each step in your derivation. T-e-6%
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