The variation of the vapor pressure of the liquid and the solids forms of a pure substance near the triple point (tp) is given by AHvap ( 1 InP=P+R T TIp and ΔΗ. subl 1 InP = Ps+ %3D tp R Calculate the temperature (K) at the triple point using the following information

Chemistry & Chemical Reactivity
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Chapter11: Intermolecular Forces And Liquids
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Problem 38GQ: The following data are the equilibrium vapor pressure of limonene, C10H16, at various temperatures....
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The variation of the vapor pressure of the liquid and the solids forms of a pure substance near the triple point (tp) is
given by
AHvap
InP= P+
1
1
%3D
tp
T
and
AH subl
1
1
InPs = PS+
tp
%3D
R
tp
Calculate the temperature (K) at the triple point using the following information
AHvap
= 34.3 KJ/mol
ΔΗ.
= 46.8 KJ/mol
subl
= 281 K
T = 204 K
P 8088 Pa
ps =103 Pa
O a. 175.88
Ob. 58.63
C. 351.76
d. 87.94
Transcribed Image Text:The variation of the vapor pressure of the liquid and the solids forms of a pure substance near the triple point (tp) is given by AHvap InP= P+ 1 1 %3D tp T and AH subl 1 1 InPs = PS+ tp %3D R tp Calculate the temperature (K) at the triple point using the following information AHvap = 34.3 KJ/mol ΔΗ. = 46.8 KJ/mol subl = 281 K T = 204 K P 8088 Pa ps =103 Pa O a. 175.88 Ob. 58.63 C. 351.76 d. 87.94
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