**Understanding the van der Waals Equation: Correction Terms 'a' and 'b'**The van der Waals equation has two correction terms, \(a\) and \(b\). Briefly describe what each of these terms individually accounts for in a real gas.---* Explanation:The van der Waals equation is an equation of state for real gases that takes into account intermolecular forces and the actual volume occupied by gas molecules. These considerations lead to deviations from the ideal gas law. The equation introduces two parameters, \(a\) and \(b\), which correct for these non-ideal behaviors:1. **Parameter \(a\)**: This term corrects for the intermolecular attractions between gas molecules. In real gases, molecules attract each other, reducing the pressure exerted on the walls of the container. The \(a\) term accounts for this by adding a correction factor that increases the measured pressure.2. **Parameter \(b\)**: This term corrects for the finite volume occupied by gas molecules. Unlike in an ideal gas, real gas molecules occupy space, which reduces the volume available for molecular movement. The \(b\) term represents the volume excluded by a mole of gas particles and adjusts the volume accordingly in the equation.By incorporating these correction terms, the van der Waals equation provides a more accurate representation of the behavior of real gases, particularly under high pressure and low temperature conditions.---*Please use this information to understand the van der Waals equation better in your studies of real gases.

Gas is a state of matter whose particles have large inter-molecular distance. Due to the presence of…

Answered: The van der Waals equation has two…

The van der Waals equation has two correction terms, a and b. Briefly describe what each of these terms individually accounts for in a real gas.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

**Understanding the van der Waals Equation: Correction Terms 'a' and 'b'**

The van der Waals equation has two correction terms, \(a\) and \(b\). Briefly describe what each of these terms individually accounts for in a real gas.

---

* Explanation:

The van der Waals equation is an equation of state for real gases that takes into account intermolecular forces and the actual volume occupied by gas molecules. These considerations lead to deviations from the ideal gas law. The equation introduces two parameters, \(a\) and \(b\), which correct for these non-ideal behaviors:

1. **Parameter \(a\)**: This term corrects for the intermolecular attractions between gas molecules. In real gases, molecules attract each other, reducing the pressure exerted on the walls of the container. The \(a\) term accounts for this by adding a correction factor that increases the measured pressure.

2. **Parameter \(b\)**: This term corrects for the finite volume occupied by gas molecules. Unlike in an ideal gas, real gas molecules occupy space, which reduces the volume available for molecular movement. The \(b\) term represents the volume excluded by a mole of gas particles and adjusts the volume accordingly in the equation.

By incorporating these correction terms, the van der Waals equation provides a more accurate representation of the behavior of real gases, particularly under high pressure and low temperature conditions.

---

*Please use this information to understand the van der Waals equation better in your studies of real gases.

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