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TABLE 16.3 sma van der Waals constants for various substances. Species a/dm-bar mol 2 a/dm . atm-mol b/dm2 mol- Helium 0.034598 0.034145 0.023733 Neon 0.21666 0.21382 0.017383 Argon 1.3483 1.3307 0.031830 Krypton 2.2836 2.2537 0.038650 Hydrogen 0.24646 0.24324 0.026665 Nitrogen 1.3661 1.3483 0.038577 Oxygen 1.3820 1.3639 0.031860 Carbon monoxide 1.4734 1.4541 0.039523 Carbon dioxide 3.6551 3.6073 0.042816 Ammonia 4.3044 4.2481 0.037847 Methane 2.3026 2.2725 0.043067 Ethane 5.5818 5.5088 0.065144 Ethene 4.6112 4.5509 0.058199 Propane 9.3919 9.2691 0.090494 Butane 13.888 13.706 0.11641 2-Methyl propane 13.328 13.153 0.11645 Pentane 19.124 18.874 0.14510 Benzene 18.876 18.629 0.11974

TABLE 16.3 sma van der Waals constants for various substances. Species a/dm-bar mol 2 a/dm . atm-mol b/dm2 mol- Helium 0.034598 0.034145 0.023733 Neon 0.21666 0.21382 0.017383 Argon 1.3483 1.3307 0.031830 Krypton 2.2836 2.2537 0.038650 Hydrogen 0.24646 0.24324 0.026665 Nitrogen 1.3661 1.3483 0.038577 Oxygen 1.3820 1.3639 0.031860 Carbon monoxide 1.4734 1.4541 0.039523 Carbon dioxide 3.6551 3.6073 0.042816 Ammonia 4.3044 4.2481 0.037847 Methane 2.3026 2.2725 0.043067 Ethane 5.5818 5.5088 0.065144 Ethene 4.6112 4.5509 0.058199 Propane 9.3919 9.2691 0.090494 Butane 13.888 13.706 0.11641 2-Methyl propane 13.328 13.153 0.11645 Pentane 19.124 18.874 0.14510 Benzene 18.876 18.629 0.11974

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Calculate the pressure (in atm) exerted by one mole of butane that is occupying 22.414 L at 273.16 K, if it were considered as an: a.) Ideal gas, b.) Van der Waals gas gaving the constants listed in Table 16.3. 

What physical property of butane accounts most for the calculated difference. 

TABLE 16.3 sma van der Waals constants for various substances. Species a/dm-bar mol 2 a/dm . atm-mol b/dm2 mol- Helium 0.034598 0.034145 0.023733 Neon 0.21666 0.21382 0.017383 Argon 1.3483 1.3307 0.031830 Krypton 2.2836 2.2537 0.038650 Hydrogen 0.24646 0.24324 0.026665 Nitrogen 1.3661 1.3483 0.038577 Oxygen 1.3820 1.3639 0.031860 Carbon monoxide 1.4734 1.4541 0.039523 Carbon dioxide 3.6551 3.6073 0.042816 Ammonia 4.3044 4.2481 0.037847 Methane 2.3026 2.2725 0.043067 Ethane 5.5818 5.5088 0.065144 Ethene 4.6112 4.5509 0.058199 Propane 9.3919 9.2691 0.090494 Butane 13.888 13.706 0.11641 2-Methyl propane 13.328 13.153 0.11645 Pentane 19.124 18.874 0.14510 Benzene 18.876 18.629 0.11974
Transcribed Image Text:TABLE 16.3 sma van der Waals constants for various substances. Species a/dm-bar mol 2 a/dm . atm-mol b/dm2 mol- Helium 0.034598 0.034145 0.023733 Neon 0.21666 0.21382 0.017383 Argon 1.3483 1.3307 0.031830 Krypton 2.2836 2.2537 0.038650 Hydrogen 0.24646 0.24324 0.026665 Nitrogen 1.3661 1.3483 0.038577 Oxygen 1.3820 1.3639 0.031860 Carbon monoxide 1.4734 1.4541 0.039523 Carbon dioxide 3.6551 3.6073 0.042816 Ammonia 4.3044 4.2481 0.037847 Methane 2.3026 2.2725 0.043067 Ethane 5.5818 5.5088 0.065144 Ethene 4.6112 4.5509 0.058199 Propane 9.3919 9.2691 0.090494 Butane 13.888 13.706 0.11641 2-Methyl propane 13.328 13.153 0.11645 Pentane 19.124 18.874 0.14510 Benzene 18.876 18.629 0.11974
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