The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation energy is 420 kJ. And at 37°C, the rate constant is 4.90 × 10–4 min–1. What is the half-life of the uncoiling at 37°C (normal body temperature)? ___________ min   b The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation energy is 420 kJ. And at 37°C, the rate constant is 4.90 × 10–4 min–1. What is the half-life of the uncoiling if the organism has a temperature of 39°C (102°F).  _________ min

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 63QAP: The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation energy is 420...
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The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation energy is 420 kJ. And at 37°C, the rate constant is 4.90 × 10–4 min–1.

What is the half-life of the uncoiling at 37°C (normal body temperature)?

___________ min

 
b

The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation energy is 420 kJ. And at 37°C, the rate constant is 4.90 × 10–4 min–1. What is the half-life of the uncoiling if the organism has a temperature of 39°C (102°F).

 _________ min

 
c

The uncoiling of deoxyribonucleic acid (DNA) is a first-order reaction. Its activation energy is 420 kJ. And at 37°C, the rate constant is 4.90 × 10-4 min-1.

At 39°C, the rate constant is 0.00139 min-1. By what factor does the rate of uncoiling increase (per °C) over this temperature interval?

 _________ times/°C rise

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