The image contains mass spectra of two isomers of C₄H₁₀O: 1-butanol and 2-butanol. The task is to match each spectrum with its corresponding compound and to identify the m/z ratio and structure for specific labeled fragments. Below are descriptions of the two mass spectra and the table that need to be completed.### Top Mass Spectrum:- **Peaks and Labels:** - **Peak 1:** Labeled with arrow 1, corresponds to a specific m/z ratio. - **Peak 2:** Labeled with arrow 2, corresponds to a specific m/z ratio.- **Axis Labels:** - X-axis: m/z (mass-to-charge ratio) - Y-axis: Relative Intensity### Bottom Mass Spectrum:- **Peaks and Labels:** - **Peak 3:** Labeled with arrow 3, corresponds to a specific m/z ratio. - **Peak 4:** Labeled with arrow 4, corresponds to a specific m/z ratio.- **Axis Labels:** - X-axis: m/z (mass-to-charge ratio) - Y-axis: Relative Intensity### Table to Complete:- There is a table with four columns labeled Fragment 1, Fragment 2, Fragment 3, and Fragment 4.- For each fragment, you need to determine: - **m/z ratio:** The mass-to-charge ratio for the fragment. - **Fragment Structure:** The molecular structure or formula of the fragment.This task involves analyzing the mass spectra to determine which peaks correspond to specific fragments of 1-butanol or 2-butanol, and filling out the table accordingly with m/z ratios and structures.

Answered: Image /qna-images/answer/bc4409d6-0e12-4430-b05a-68370e1b92cd.jpg

The two mass spectra below correspond to two isomers of C4H10O: 1-butanol and 2-butanol. Match the spectrum with the appropriate compound. Place the m/z ratio and the structures for the labeled fragments in the table below. 100- Compound 00 GO 1 40 20- o ... p..r 10 20 30 40 50 60 70 80 90 100 m/7 100 - Compound 3 80 60 40 20 - 10 15 20 25 30 35 40 45 50 55 60 65 70 75 m/z Fragment 1 Fragment 2 Fragment 3 Fragment 4 m/z Fragment Relative Intensity Re-ative Intersity F8

The two mass spectra below correspond to two isomers of C4H10O: 1-butanol and 2-butanol. Match the spectrum with the appropriate compound. Place the m/z ratio and the structures for the labeled fragments in the table below. 100- Compound 00 GO 1 40 20- o ... p..r 10 20 30 40 50 60 70 80 90 100 m/7 100 - Compound 3 80 60 40 20 - 10 15 20 25 30 35 40 45 50 55 60 65 70 75 m/z Fragment 1 Fragment 2 Fragment 3 Fragment 4 m/z Fragment Relative Intensity Re-ative Intersity F8

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

interpret/identify the peaks and their characteristics. (ex. C=O, 4H, doublet) compound name: isopentyl acetate (C7H14O2)
Determine the molecular ion peak in the mass spectra below.
Assign molecules B, C, D and F to the correct mass spectrum and provide the structure of thebase peak. draw the assigned molecules
After submitting a sample for mass spectral analysis you are given the following spectrum: 100 80 - 60 40 20 – 10 20 30 40 50 60 70 80 m/z You know that your sample is either 3-pentanone or 3-pentanol. OH 3-pentanone 3-pentanol Part A: How could you use the mass spectrum above as your only means to determine if your sample is either 3-pentanone or 3- pentanol? Note that the spectrum above lacks a molecular ion. Part B: What is the identity of the sample which provided you with spectrum above: 3-pentanone or 3-pentanol? Relative Intensity
1. What do you suppose is the molecular weight of the molecule that gives the mass spectrum below? 27 Hai 55 26 45 30 40 50 Rel Abund 100r 80- 60- 40- 20- 0- m/z0 10 Rel Abund = Relative Abundance Formula 1: 20 Formula 2: Formula 3: m/z = mass divided by charge 3. What is the base peak? 2. Provide three different molecular formulas (organic molecules, please) that are possible for a molecule with the molecular weight you have chosen. What are the degrees of unsaturation (SODAR) for each? Degrees of unsaturation: Degrees of unsaturation: Degrees of unsaturation: 60 4. Draw a possible molecule for each formula. based on Formula 1 5. Which structure do you think is correct? 72 70 based on Formula 2 80 What mass is lost from the molecular ion to get to the base peak? 90 100 based on Formula 3
Relative Intensity 100 CH3 (CH₂)3CH3 LI 40 80 40 20 0++ MS-IW-3004 10 15 20 25 30 35 Using this MS, what is the molecular weight of this compound O 71 O 73 45 50 55 m/z O 72 O There is not enough information 60 65 70 75
4. Draw a possible molecule for each formula. based on Formula 1 5. Which structure do you think is correct? based on Formula 2 based on Formula 3
Mass spectrometry: For the compound shown below, predict the m/z of the base peak. base peak? O 84 O 70 O 55 O 69 O 56 esc f4 fs # 8 2 3 4 6. 8. W T Y 4 A F G H C V