The tetrachloroplatinate anion has Dah symmetry. Use sketches to show that the Pt dxy orbital has B2g symmetry and а. the d,2-y2 orbital has Big symmetry. (Hint: show how the signs of the orbital lobes change with each symmetry operation.) b. Explain qualitatively why the Pt dxz and dyz Oorbitals are degenerate. CI-Pt-CI

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Chapter1: Chemical Foundations
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The tetrachloroplatinate anion has D4h symmetry.
Use sketches to show that the Pt dxy orbital has B2g symmetry and
the d,2-y2 orbital has B1g symmetry. (Hint: show how the signs of
the orbital lobes change with each symmetry operation.)
b. Explain qualitatively why the Pt dxz and dyz orbitals are degenerate.
CI
12-
а.
CI-Pt-CI
CI
Transcribed Image Text:The tetrachloroplatinate anion has D4h symmetry. Use sketches to show that the Pt dxy orbital has B2g symmetry and the d,2-y2 orbital has B1g symmetry. (Hint: show how the signs of the orbital lobes change with each symmetry operation.) b. Explain qualitatively why the Pt dxz and dyz orbitals are degenerate. CI 12- а. CI-Pt-CI CI
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