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2. The complex [Mo(CNH)8]** is an eight-coordinate complex discussed in Angew. Chem. Int. Ed. 2020, 59, 1 - 5. The ligand used is isocyanate (RCN where R = H in this case but can be many different alkyl substituents). You may wish to (but are not required to) read the paper while answering the following questions.

2. The complex [Mo(CNH)8]** is an eight-coordinate complex discussed in Angew. Chem. Int. Ed. 2020, 59, 1 - 5. The ligand used is isocyanate (RCN where R = H in this case but can be many different alkyl substituents). You may wish to (but are not required to) read the paper while answering the following questions.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Point group of square Antiprismatic is D4d

2. The complex [Mo(CNH)s]4+ is an eight-coordinate complex discussed in Angew. Chem. Int. Ed. 2020, 59, 1 – 5. The ligand used is isocyanate (RCN where R = H in this case but can be many different alkyl substituents). You may wish to (but are not required to) read the paper while answering the following questions. Ideal square antiprism b) While it is always possible to place a coordinate axis at each atom to find all atomic motions in a molecule, sometimes (like in this case) this would lead to a very large number of vibrational modes. We can simplify the system considerably by ONLY considering the stretching vibrational modes of the C = N bond. Do this by drawing eight vectors (the 8 vectors shown here) and finding their symmetry in the usual way. Which stretching vibrations will be IR active in the point group you determined in Ideal square antiprism (side view with stretching vectors) part a?
Transcribed Image Text:2. The complex [Mo(CNH)s]4+ is an eight-coordinate complex discussed in Angew. Chem. Int. Ed. 2020, 59, 1 – 5. The ligand used is isocyanate (RCN where R = H in this case but can be many different alkyl substituents). You may wish to (but are not required to) read the paper while answering the following questions. Ideal square antiprism b) While it is always possible to place a coordinate axis at each atom to find all atomic motions in a molecule, sometimes (like in this case) this would lead to a very large number of vibrational modes. We can simplify the system considerably by ONLY considering the stretching vibrational modes of the C = N bond. Do this by drawing eight vectors (the 8 vectors shown here) and finding their symmetry in the usual way. Which stretching vibrations will be IR active in the point group you determined in Ideal square antiprism (side view with stretching vectors) part a?
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