The stronger the IMFs the higher the boiling point (a) Draw structures for the two molecules, name all molecules and list the types of IMFs that are present in each compound in the liquid stat. bp (1) bp (2) Sketches: Names: IMFs: (b) Do you expect vapor pressure for these compounds (at the some common temperature at which all of them are in liquid state) to follow the same trend? Why or why not? Sketches: < 2. Pick 2 more molecules to show how the length of extended carbon-carbon chain affects bp: Longer extended carbon-carbon chain has_ boiling point a) Draw structures for the two molecules, write the names for all molecules and indicate the IMFS present in each case. bp (1) Names: IMFs: bp (3) bp (2) b) Justify this trend from the point of view of IMFs only. bp (3)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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3 / 6
Sketches:
1. Pick two more molecules from the table that help you illustrate the following trend:
The stronger the IMFs the higher the boiling point
(a) Draw structures for the two molecules, name all molecules and list the types of IMFs that
are present in each compound in the liquid stat.
bp (1)
75%
Sketches:
Names:
+
IMFs:
Names:
IMFs:
(b) Do you expect vapor pressure for these compounds (at the some common temperature at
which all of them are in liquid state) to follow the same trend? Why or why not?
bp (2)
i
2. Pick 2 more molecules to show how the length of extended carbon-carbon chain affects bp:
Longer extended carbon-carbon chain has,
boiling point
a) Draw structures for the two molecules, write the names for all molecules and indicate
the IMFS present in each case.
bp (1)
General Chemistry 1
<
bp (2)
bp (3)
b) Justify this trend from the point of view of IMFs only.
bp (3)
Transcribed Image Text:3 / 6 Sketches: 1. Pick two more molecules from the table that help you illustrate the following trend: The stronger the IMFs the higher the boiling point (a) Draw structures for the two molecules, name all molecules and list the types of IMFs that are present in each compound in the liquid stat. bp (1) 75% Sketches: Names: + IMFs: Names: IMFs: (b) Do you expect vapor pressure for these compounds (at the some common temperature at which all of them are in liquid state) to follow the same trend? Why or why not? bp (2) i 2. Pick 2 more molecules to show how the length of extended carbon-carbon chain affects bp: Longer extended carbon-carbon chain has, boiling point a) Draw structures for the two molecules, write the names for all molecules and indicate the IMFS present in each case. bp (1) General Chemistry 1 < bp (2) bp (3) b) Justify this trend from the point of view of IMFs only. bp (3)
3
F6
F7
&
7
D
General Chemistry 1
3. Use the table to predict how the molecular surface area affects boiling point. Think about a
sphere-it has the lowest surface area for the given volume. The closer the molecular shape
to a sphere the lower the surface area. Pick two more molecules from the table - with the
similar MM's and similar IMFs but with different surface areas - to illustrate how the surface
area affects bp.
F8
A molecule with a smaller surface area has_
boiling point
a) Draw structures for the two more molecules, name all molecules, and list the types of
intermolecular forces that are present in each case.
bp (1) <
<
Sketches:
Names:
IMFs:
b) Justify this trend from the point of view of IMFs only.
4. Now that you've looked at all three trends you are ready to compare boiling points!
(a) List the following compounds in order of decreasing boiling points.
A.
i i i
OH
a
8
(b) Justify your answer using the trends we just discussed.
8
bp (2)
OH
F9
02
(
bp () > bp (_________) > bp (_________) > bp (_________) > bp (________)
9
F10
*-
F11
)
O
P
D.
*+
F12
OH
-
bp (3)
C
E.
PrtSc
Insert
}
1
Delete
Backspace
►/11
Num
Lock
7
Transcribed Image Text:3 F6 F7 & 7 D General Chemistry 1 3. Use the table to predict how the molecular surface area affects boiling point. Think about a sphere-it has the lowest surface area for the given volume. The closer the molecular shape to a sphere the lower the surface area. Pick two more molecules from the table - with the similar MM's and similar IMFs but with different surface areas - to illustrate how the surface area affects bp. F8 A molecule with a smaller surface area has_ boiling point a) Draw structures for the two more molecules, name all molecules, and list the types of intermolecular forces that are present in each case. bp (1) < < Sketches: Names: IMFs: b) Justify this trend from the point of view of IMFs only. 4. Now that you've looked at all three trends you are ready to compare boiling points! (a) List the following compounds in order of decreasing boiling points. A. i i i OH a 8 (b) Justify your answer using the trends we just discussed. 8 bp (2) OH F9 02 ( bp () > bp (_________) > bp (_________) > bp (_________) > bp (________) 9 F10 *- F11 ) O P D. *+ F12 OH - bp (3) C E. PrtSc Insert } 1 Delete Backspace ►/11 Num Lock 7
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