The stronger the IMFs the higher the boiling point (a) Draw structures for the two molecules, name all molecules and list the types of IMFs that are present in each compound in the liquid stat. bp (1) bp (2) Sketches: Names: IMFs: (b) Do you expect vapor pressure for these compounds (at the some common temperature at which all of them are in liquid state) to follow the same trend? Why or why not? Sketches: < 2. Pick 2 more molecules to show how the length of extended carbon-carbon chain affects bp: Longer extended carbon-carbon chain has_ boiling point a) Draw structures for the two molecules, write the names for all molecules and indicate the IMFS present in each case. bp (1) Names: IMFs: bp (3) bp (2) b) Justify this trend from the point of view of IMFs only. bp (3)
States of Matter
The substance that constitutes everything in the universe is known as matter. Matter comprises atoms which in turn are composed of electrons, protons, and neutrons. Different atoms combine together to give rise to molecules that act as a foundation for all kinds of substances. There are five states of matter based on their energies of attraction, namely solid, liquid, gases, plasma, and BEC (Bose-Einstein condensates).
Chemical Reactions and Equations
When a chemical species is transformed into another chemical species it is said to have undergone a chemical reaction. It consists of breaking existing bonds and forming new bonds by changing the position of electrons. These reactions are best explained using a chemical equation.
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Sketches:
1. Pick two more molecules from the table that help you illustrate the following trend:
The stronger the IMFs the higher the boiling point
(a) Draw structures for the two molecules, name all molecules and list the types of IMFs that
are present in each compound in the liquid stat.
bp (1)
75%
Sketches:
Names:
+
IMFs:
Names:
IMFs:
(b) Do you expect vapor pressure for these compounds (at the some common temperature at
which all of them are in liquid state) to follow the same trend? Why or why not?
bp (2)
i
2. Pick 2 more molecules to show how the length of extended carbon-carbon chain affects bp:
Longer extended carbon-carbon chain has,
boiling point
a) Draw structures for the two molecules, write the names for all molecules and indicate
the IMFS present in each case.
bp (1)
General Chemistry 1
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bp (2)
bp (3)
b) Justify this trend from the point of view of IMFs only.
bp (3)"
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F6
F7
&
7
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General Chemistry 1
3. Use the table to predict how the molecular surface area affects boiling point. Think about a
sphere-it has the lowest surface area for the given volume. The closer the molecular shape
to a sphere the lower the surface area. Pick two more molecules from the table - with the
similar MM's and similar IMFs but with different surface areas - to illustrate how the surface
area affects bp.
F8
A molecule with a smaller surface area has_
boiling point
a) Draw structures for the two more molecules, name all molecules, and list the types of
intermolecular forces that are present in each case.
bp (1) <
<
Sketches:
Names:
IMFs:
b) Justify this trend from the point of view of IMFs only.
4. Now that you've looked at all three trends you are ready to compare boiling points!
(a) List the following compounds in order of decreasing boiling points.
A.
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OH
a
8
(b) Justify your answer using the trends we just discussed.
8
bp (2)
OH
F9
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bp () > bp (_________) > bp (_________) > bp (_________) > bp (________)
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D.
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F12
OH
-
bp (3)
C
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