The reaction shown in Figure 10-8 produces only one solvolysis product. Carbocation rearrangement does not occur because O the original carbocation is resonance stabilized. O the intermediate is too sterically hindered to rearrange. O bromide ion is not a good enough leaving group to promote carbocation rearrangement O the solvent is protic which will inhibit rearrangement.
The reaction shown in Figure 10-8 produces only one solvolysis product. Carbocation rearrangement does not occur because O the original carbocation is resonance stabilized. O the intermediate is too sterically hindered to rearrange. O bromide ion is not a good enough leaving group to promote carbocation rearrangement O the solvent is protic which will inhibit rearrangement.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:The reaction shown in Figure 10-8
produces only one solvolysis product.
Carbocation rearrangement does not
occur because
O the original carbocation is resonance
stabilized.
O the intermediate is too sterically hindered
to rearrange.
bromide ion is not a good enough leaving
group to promote carbocation
rearrangement
O the solvent is protic which will inhibit
rearrangement.

Transcribed Image Text:Figure
10-8
Br
CH3OH
heat
OCH 3
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