The reaction of NO2(g) and CO(g) is thought to occur in two steps to give NO and CO2: Step 1: Slow NO2(g) + NO2(g) n NO(g) + NO3(g) Step 2: Fast NO3(g) + CO(g) n NO2(g) + CO2(g) (a) Show that the elementary steps add up to give the overall, stoichiometric equation. (b) What is the molecularity of each step? (c) For this mechanism to be consistent with kinetic data, what must be the experimental rate equation? (d) Identify any intermediates in this reaction
The reaction of NO2(g) and CO(g) is thought to occur in two steps to give NO and CO2: Step 1: Slow NO2(g) + NO2(g) n NO(g) + NO3(g) Step 2: Fast NO3(g) + CO(g) n NO2(g) + CO2(g) (a) Show that the elementary steps add up to give the overall, stoichiometric equation. (b) What is the molecularity of each step? (c) For this mechanism to be consistent with kinetic data, what must be the experimental rate equation? (d) Identify any intermediates in this reaction
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The reaction of NO2(g) and CO(g) is thought to
occur in two steps to give NO and CO2:
Step 1: Slow
NO2(g) + NO2(g) n NO(g) + NO3(g)
Step 2: Fast
NO3(g) + CO(g) n NO2(g) + CO2(g)
(a) Show that the elementary steps add up to give
the overall, stoichiometric equation.
(b) What is the molecularity of each step?
(c) For this mechanism to be consistent with
kinetic data, what must be the experimental
rate equation?
(d) Identify any intermediates in this reaction.
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