The three-step mechanism outlined in the table below has been proposed for the reaction of chlorine and chloroform. a) Write the equation for the overall reaction. b) Write the rate law for the overall reaction. c) Calculate the rate constant for the overall reaction (include units). elementary steps rate constant (without units) equilibrium constant 1) Cl2(g) <-- --> 2 Cl(g) k1 = 4.8 x 103 Keq1 = 1.2 2) Cl(g) + CHCl3(g) --> HCl(g) + CCl3(g) k2 = 1.3 x 10-2 3) CCl3 + Cl(g) --> CCl4 k3 = 2.7 x 102
The three-step mechanism outlined in the table below has been proposed for the reaction of chlorine and chloroform. a) Write the equation for the overall reaction. b) Write the rate law for the overall reaction. c) Calculate the rate constant for the overall reaction (include units). elementary steps rate constant (without units) equilibrium constant 1) Cl2(g) <-- --> 2 Cl(g) k1 = 4.8 x 103 Keq1 = 1.2 2) Cl(g) + CHCl3(g) --> HCl(g) + CCl3(g) k2 = 1.3 x 10-2 3) CCl3 + Cl(g) --> CCl4 k3 = 2.7 x 102
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The three-step mechanism outlined in the table below has been proposed for the reaction of chlorine and chloroform.
a) Write the equation for the overall reaction.
b) Write the rate law for the overall reaction.
c) Calculate the rate constant for the overall reaction (include units).
elementary steps | rate constant (without units) | equilibrium constant | |
1) | Cl2(g) <-- --> 2 Cl(g) | k1 = 4.8 x 103 | Keq1 = 1.2 |
2) | Cl(g) + CHCl3(g) --> HCl(g) + CCl3(g) | k2 = 1.3 x 10-2 | |
3) | CCl3 + Cl(g) --> CCl4 | k3 = 2.7 x 102 |
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