The reaction, A+B P+Q ...(Q-1) is carried out at 120°C in a lab scale reactor. The feed is equimolar and the initial concentration of A is 0.65 mol.1-¹. The observed fractional concentration of A remaining in the reactor is given in Table Q2. Table Q2. The kinetic data. Time (min) | CA/Cao Time (min) | Ca/Cao 40 0.941 167 0.790 82 0.885 211 0.750 113 0.848 235 0.730 138 0.820 (a) Apply differential method and evaluate the order of reaction. (b) Determine the reaction rate constant.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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The reaction,
A+B →P+Q
...(Q-1)
is carried out at 120°C in a lab scale reactor. The feed is equimolar and the initial
concentration of A is 0.65 mol.1-¹. The observed fractional concentration of A remaining
in the reactor is given in Table Q2.
Table Q2. The kinetic data.
Time (min)
40
CACAO Time (min) | Ca/Cao
0.941
167
0.790
82
0.885
211
0.750
113
0.848
235
0.730
138
0.820
(a) Apply differential method and evaluate the order of reaction.
(b) Determine the reaction rate constant.
Transcribed Image Text:2 The reaction, A+B →P+Q ...(Q-1) is carried out at 120°C in a lab scale reactor. The feed is equimolar and the initial concentration of A is 0.65 mol.1-¹. The observed fractional concentration of A remaining in the reactor is given in Table Q2. Table Q2. The kinetic data. Time (min) 40 CACAO Time (min) | Ca/Cao 0.941 167 0.790 82 0.885 211 0.750 113 0.848 235 0.730 138 0.820 (a) Apply differential method and evaluate the order of reaction. (b) Determine the reaction rate constant.
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