The formation of NO from Na and O is to be carried out in a small batch reactor. As a flrst approximation, we shall consider that the reaction time is more rapid than the time of cylinder compression, consequently, the reaction takes place isothermally in car cylinder at 2700 K, in a constant volume reactor (cylinder) and under a pressure of 20 atm, the initial concentration of Na is 0.0696 mol/liter. By a specifying constant volume, we are assuming that reaction take place rapidly with respect to the movement of the piston in the cylinder. Consider that the feed consists of 77% N2, 15% O, and 8% other gases, which may be considered inert. At this temperature the equilibrium constant (Ke-0.01). The reaction is reversible: Na + 0, + 2NO With a rate equation: Cho -TN, = k(CN, Co, Ke Calculate: a) The equilibrium conversion of N2. b) The time required to achieve 80% of the equilibrium conversion. The formation reaction rate liter constant k at this temperature is 1.11 mot.h

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
icon
Related questions
Question
The formation of NO from Na and O is to be carried out in a small batch reactor. As a first approximation,
we shall consider that the reaction time is more rapid than the time of cylinder compression,
consequently, the reaction takes place isothermally in car eylinder at 2700 K, in a constant volume reactor
(cylinder) and under a pressure of 20 atm, the initial concentration of N2 is 0.0696 mol/liter. By a
specifying constant volume, we are assuming that reaction take place rapidly with respect to the
movement of the piston in the cylinder.
Consider that the feed consists of 77% N2, 15% Oz and 8% other gases, which may be considered inert.
At this temperature the equilibrium constant (Ke-0.01). The reaction is reversible:
Na + 0z + 2NO
With a rate equation:
Cho
-TN, = k ( CN, Co,
Ke
Calculate:
a) The equilibrium conversion of N2.
b) The time required to achieve 80% of the equilibrium conversion. The formation reaction rate-
constant k at this temperature is 1.11
liter
mol.h'
Hint:
dx
Jo ax2+bx+c
-In(4.P); b2 > 4ac;
px-q
a(p-q)
-BFVD-4ac
where, p, q =
2a
Transcribed Image Text:The formation of NO from Na and O is to be carried out in a small batch reactor. As a first approximation, we shall consider that the reaction time is more rapid than the time of cylinder compression, consequently, the reaction takes place isothermally in car eylinder at 2700 K, in a constant volume reactor (cylinder) and under a pressure of 20 atm, the initial concentration of N2 is 0.0696 mol/liter. By a specifying constant volume, we are assuming that reaction take place rapidly with respect to the movement of the piston in the cylinder. Consider that the feed consists of 77% N2, 15% Oz and 8% other gases, which may be considered inert. At this temperature the equilibrium constant (Ke-0.01). The reaction is reversible: Na + 0z + 2NO With a rate equation: Cho -TN, = k ( CN, Co, Ke Calculate: a) The equilibrium conversion of N2. b) The time required to achieve 80% of the equilibrium conversion. The formation reaction rate- constant k at this temperature is 1.11 liter mol.h' Hint: dx Jo ax2+bx+c -In(4.P); b2 > 4ac; px-q a(p-q) -BFVD-4ac where, p, q = 2a
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 5 steps with 5 images

Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The