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The reaction 3ClO-(aq) → ClO3-(aq) + 2Cl-(aq) has been proposed to occur by the following mechanism: ClO-(aq) + ClO-( aq)→ ClO2-(aq) + Cl-( aq) (slow) ClO2-(aq) + ClO-(aq) → ClO3-(aq) + Cl-(aq) (fast) Which rate law is consistent with this mechanism?

The reaction 3ClO-(aq) → ClO3-(aq) + 2Cl-(aq) has been proposed to occur by the following mechanism: ClO-(aq) + ClO-( aq)→ ClO2-(aq) + Cl-( aq) (slow) ClO2-(aq) + ClO-(aq) → ClO3-(aq) + Cl-(aq) (fast) Which rate law is consistent with this mechanism?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The reaction

3ClO-(aq) → ClO3-(aq) + 2Cl-(aq)

has been proposed to occur by the following mechanism:

ClO-(aq) + ClO-( aq)→ ClO2-(aq) + Cl-( aq) (slow)

ClO2-(aq) + ClO-(aq) → ClO3-(aq) + Cl-(aq) (fast)

Which rate law is consistent with this mechanism?


 

a.

rate = k [Cl-][ClO-]2

b.

rate = k [ClO-]2

c.

rate = k [ClO3-]3

d.

rate = k [ClO2-][ClO-]

e.

rate = k[ClO-]

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