The rate for the oxidation of iron(II) by cerium(IV) Ce** (aq) + Fe²* (aq) → Ce* (aq) + Fe* (aq) is measured at several different initial concentrations of the two reactants: [Ce**] (mol L-') [Fe?+] (mol L-') Rate (mol L-s-') 1.1 x 10-5 1.8 x 10-5 2.0 x 10-7 1.1 x 10-5 2.8 x 10-5 3.1 x 10-7 3.4 x 10-5 2.8 x 10-5 9.5 x 10-7 (a) Write the rate expression for this reaction. (b) Calculate the rate constant k and give its units. (c) Predict the initial reaction rate for a solution in which [Ce**] is 2.6 x 10-5 M and [Fe²*] is 1.3 × 10-5 M.

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The rate for the oxidation of iron(II) by cerium(IV)
Ce** (aq) + Fe²* (aq) → Ce* (aq) + Fe* (aq)
is measured at several different initial concentrations of
the two reactants:
[Ce**]
(mol L-')
[Fe?+]
(mol L-')
Rate
(mol L-s-')
1.1 x 10-5
1.8 x 10-5
2.0 x 10-7
1.1 x 10-5
2.8 x 10-5
3.1 x 10-7
3.4 x 10-5
2.8 x 10-5
9.5 x 10-7
(a) Write the rate expression for this reaction.
(b) Calculate the rate constant k and give its units.
(c) Predict the initial reaction rate for a solution in which
[Ce**] is 2.6 x 10-5 M and [Fe²*] is 1.3 × 10-5 M.
Transcribed Image Text:The rate for the oxidation of iron(II) by cerium(IV) Ce** (aq) + Fe²* (aq) → Ce* (aq) + Fe* (aq) is measured at several different initial concentrations of the two reactants: [Ce**] (mol L-') [Fe?+] (mol L-') Rate (mol L-s-') 1.1 x 10-5 1.8 x 10-5 2.0 x 10-7 1.1 x 10-5 2.8 x 10-5 3.1 x 10-7 3.4 x 10-5 2.8 x 10-5 9.5 x 10-7 (a) Write the rate expression for this reaction. (b) Calculate the rate constant k and give its units. (c) Predict the initial reaction rate for a solution in which [Ce**] is 2.6 x 10-5 M and [Fe²*] is 1.3 × 10-5 M.
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