The rate constant k for a certain reaction is measured at two different temperatures: temperature k 362.0 °C 1.3 x 1010 423.0 °C 1.7 x 10¹0 Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E for this reaction. Round your answer to 2 significant digits. kJ ☐ E = mol x10 X 5
The rate constant k for a certain reaction is measured at two different temperatures: temperature k 362.0 °C 1.3 x 1010 423.0 °C 1.7 x 10¹0 Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E for this reaction. Round your answer to 2 significant digits. kJ ☐ E = mol x10 X 5
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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![### Example Problem on Calculating Activation Energy
The rate constant \( k \) for a certain reaction is measured at two different temperatures:
| Temperature (\( \degree C \)) | \( k \) (s\(^{-1}\)) |
|-------------------------------|-----------------------------|
| 362.0 | \( 1.3 \times 10^{10} \) |
| 423.0 | \( 1.7 \times 10^{10} \) |
Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy \( E_a \) for this reaction.
Round your answer to 2 significant digits.
#### Arrhenius Equation
The Arrhenius equation is expressed as:
\[ k = A \exp \left( \frac{-E_a}{RT} \right) \]
where:
- \( k \) is the rate constant,
- \( A \) is the pre-exponential factor,
- \( E_a \) is the activation energy,
- \( R \) is the gas constant (8.314 J/mol·K),
- \( T \) is the temperature in Kelvin.
#### Calculating Activation Energy
To find the activation energy, use the logarithmic form of the Arrhenius equation:
\[ \ln \left( \frac{k_2}{k_1} \right) = \frac{-E_a}{R} \left( \frac{1}{T_2} - \frac{1}{T_1} \right) \]
Rearranging for \( E_a \):
\[ E_a = - \frac{R \ln \left( \frac{k_2}{k_1} \right)}{\left( \frac{1}{T_2} - \frac{1}{T_1} \right)} \]
First, convert the temperatures from Celsius to Kelvin:
\[ T_1 = 362.0 + 273.15 = 635.15 \, \text{K} \]
\[ T_2 = 423.0 + 273.15 = 696.15 \, \text{K} \]
Let's plug in the values:
\[ \ln \left( \frac{1.7 \times 10^{10}}{1.3 \times 10^{10}} \right) = \ln \left( \frac{1.7}{1](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe361a5c2-e3a6-4cd8-bee8-5dcb720cb10b%2Fae8792b4-e793-402b-8cde-84641d7f1c58%2F7a9850vm_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Example Problem on Calculating Activation Energy
The rate constant \( k \) for a certain reaction is measured at two different temperatures:
| Temperature (\( \degree C \)) | \( k \) (s\(^{-1}\)) |
|-------------------------------|-----------------------------|
| 362.0 | \( 1.3 \times 10^{10} \) |
| 423.0 | \( 1.7 \times 10^{10} \) |
Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy \( E_a \) for this reaction.
Round your answer to 2 significant digits.
#### Arrhenius Equation
The Arrhenius equation is expressed as:
\[ k = A \exp \left( \frac{-E_a}{RT} \right) \]
where:
- \( k \) is the rate constant,
- \( A \) is the pre-exponential factor,
- \( E_a \) is the activation energy,
- \( R \) is the gas constant (8.314 J/mol·K),
- \( T \) is the temperature in Kelvin.
#### Calculating Activation Energy
To find the activation energy, use the logarithmic form of the Arrhenius equation:
\[ \ln \left( \frac{k_2}{k_1} \right) = \frac{-E_a}{R} \left( \frac{1}{T_2} - \frac{1}{T_1} \right) \]
Rearranging for \( E_a \):
\[ E_a = - \frac{R \ln \left( \frac{k_2}{k_1} \right)}{\left( \frac{1}{T_2} - \frac{1}{T_1} \right)} \]
First, convert the temperatures from Celsius to Kelvin:
\[ T_1 = 362.0 + 273.15 = 635.15 \, \text{K} \]
\[ T_2 = 423.0 + 273.15 = 696.15 \, \text{K} \]
Let's plug in the values:
\[ \ln \left( \frac{1.7 \times 10^{10}}{1.3 \times 10^{10}} \right) = \ln \left( \frac{1.7}{1
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