The rate constant k for a certain reaction is measured at two different temperatures: temperature k 362.0 °C 1.3 x 1010 423.0 °C 1.7 x 10¹0 Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E for this reaction. Round your answer to 2 significant digits. kJ ☐ E = mol x10 X 5

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
100%
Practice Pack
### Example Problem on Calculating Activation Energy

The rate constant \( k \) for a certain reaction is measured at two different temperatures:

| Temperature (\( \degree C \)) | \( k \) (s\(^{-1}\))         |
|-------------------------------|-----------------------------|
| 362.0                         | \( 1.3 \times 10^{10} \)    |
| 423.0                         | \( 1.7 \times 10^{10} \)    |

Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy \( E_a \) for this reaction.

Round your answer to 2 significant digits.

#### Arrhenius Equation

The Arrhenius equation is expressed as:
\[ k = A \exp \left( \frac{-E_a}{RT} \right) \]

where:
- \( k \) is the rate constant,
- \( A \) is the pre-exponential factor,
- \( E_a \) is the activation energy,
- \( R \) is the gas constant (8.314 J/mol·K),
- \( T \) is the temperature in Kelvin.

#### Calculating Activation Energy

To find the activation energy, use the logarithmic form of the Arrhenius equation:
\[ \ln \left( \frac{k_2}{k_1} \right) = \frac{-E_a}{R} \left( \frac{1}{T_2} - \frac{1}{T_1} \right) \]

Rearranging for \( E_a \):
\[ E_a = - \frac{R \ln \left( \frac{k_2}{k_1} \right)}{\left( \frac{1}{T_2} - \frac{1}{T_1} \right)} \]

First, convert the temperatures from Celsius to Kelvin:
\[ T_1 = 362.0 + 273.15 = 635.15 \, \text{K} \]
\[ T_2 = 423.0 + 273.15 = 696.15 \, \text{K} \]

Let's plug in the values:
\[ \ln \left( \frac{1.7 \times 10^{10}}{1.3 \times 10^{10}} \right) = \ln \left( \frac{1.7}{1
Transcribed Image Text:### Example Problem on Calculating Activation Energy The rate constant \( k \) for a certain reaction is measured at two different temperatures: | Temperature (\( \degree C \)) | \( k \) (s\(^{-1}\)) | |-------------------------------|-----------------------------| | 362.0 | \( 1.3 \times 10^{10} \) | | 423.0 | \( 1.7 \times 10^{10} \) | Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy \( E_a \) for this reaction. Round your answer to 2 significant digits. #### Arrhenius Equation The Arrhenius equation is expressed as: \[ k = A \exp \left( \frac{-E_a}{RT} \right) \] where: - \( k \) is the rate constant, - \( A \) is the pre-exponential factor, - \( E_a \) is the activation energy, - \( R \) is the gas constant (8.314 J/mol·K), - \( T \) is the temperature in Kelvin. #### Calculating Activation Energy To find the activation energy, use the logarithmic form of the Arrhenius equation: \[ \ln \left( \frac{k_2}{k_1} \right) = \frac{-E_a}{R} \left( \frac{1}{T_2} - \frac{1}{T_1} \right) \] Rearranging for \( E_a \): \[ E_a = - \frac{R \ln \left( \frac{k_2}{k_1} \right)}{\left( \frac{1}{T_2} - \frac{1}{T_1} \right)} \] First, convert the temperatures from Celsius to Kelvin: \[ T_1 = 362.0 + 273.15 = 635.15 \, \text{K} \] \[ T_2 = 423.0 + 273.15 = 696.15 \, \text{K} \] Let's plug in the values: \[ \ln \left( \frac{1.7 \times 10^{10}}{1.3 \times 10^{10}} \right) = \ln \left( \frac{1.7}{1
Expert Solution
video

Learn your way

Includes step-by-step video

steps

Step by step

Solved in 3 steps with 1 images

Blurred answer
Knowledge Booster
Reaction Rates
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY